Manganese-catalyzed intermolecular C-H/C-H coupling of carbonyls and heteroarenes

被引：25
|
作者：
Hattori, Keika [1 ,2 ]
Ziadi, Asraa [1 ,2 ]
Itami, Kenichiro [1 ,2 ,3 ]
Yamaguchi, Junichiro [1 ,2 ]
机构：
[1] Nagoya Univ, Inst Transformat Biomol WPI ITbM, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[3] Nagoya Univ, JST, ERATO, Itami Mol Nanocarbon Project,Chikusa Ku, Nagoya, Aichi 4648602, Japan
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 31期
关键词：
ALPHA-ARYLATION; TERMINAL ALKYNES; INDOLE; ACETATE; CYCLIZATIONS; SCOPE; ACID; DERIVATIVES; INHIBITORS; KETONES;
D O I：
10.1039/c4cc01376j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Manganese-catalyzed intermolecular C-H/C-H coupling of carbonyls and heteroarenes has been developed. The presence of NaIO4 as an oxidant is crucial for the catalytic reaction. These new, inexpensive reaction conditions allow the gram-scale synthesis of a-heteroaryl carboxylic acids.
引用
收藏
页码：4105 / 4107
页数：3
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