Low-temperature sintering and microwave dielectric properties of LiF-doped Ba(Mg1/2W1/2)O3-TiO2 ceramics

被引:10
作者
Bai, Xue-Jiao [1 ]
Liu, Peng [1 ]
Fu, Zhi-Fen [1 ]
Guo, Bao-Chun [1 ]
机构
[1] Shaanxi Normal Univ, Coll Phys & Informat Technol, Xian 710062, Peoples R China
基金
中国国家自然科学基金;
关键词
LTCC; Microwave dielectric ceramics; LiF sintering aid; Perovskite; STABILITY; CA; SR; BA; YB;
D O I
10.1016/j.jallcom.2016.01.147
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Ba(Mg1/2W1/2)O-3 (BMW)-x wt% LiF (x = 2.0, 4.0, 6.0, 8.0) ceramics were prepared by a conventional solid-state route. The effects of LiF addition on the sinterability, crystal structure, microstructures and microwave dielectric properties of BMW ceramics were investigated. With an amount of LiF addition, the sintering temperature of the ceramics was reduced to below 960 degrees C from 1550 degrees C without degradation of microwave dielectric properties, due to the enhancement of the apparent density at low temperature by liquid phase sintering. On this basis, TiO2 was used to adjust the temperature coefficient of resonant frequency, optimized microwave dielectric properties with epsilon(r) = 20, Qxf = 48,000 GHz, and tau(f) = 1.2 ppm/degrees C for 0.96 BMW-0.04 TiO2-4.0 wt% LiF composition. With low sintering temperature and good dielectric properties, these LiF-doped ceramics are promising materials for LTCC integration applications. (c) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:146 / 150
页数:5
相关论文
共 19 条
  • [1] Evidence of the formation of a new rock-salt type compound Li2MgTiO4 and of its role on the properties of the Li doped MgTiO3
    Bernard, J.
    Houivet, D.
    Hervieu, A.
    Haussonne, J. M.
    [J]. SOLID STATE SCIENCES, 2006, 8 (06) : 598 - 605
  • [2] Microwave dielectric properties of A1-3x/2Lax(Mg1/2W1/2)O3 (A = Ba, Sr, Ca; 0.0 ≤ x ≤ 0.05) double perovskites
    Bian, J. J.
    Yan, K.
    Dong, Y. F.
    [J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2008, 147 (01): : 27 - 34
  • [3] Structural stability and microwave dielectric properties of (1-x)Ba(Mg1/2W1/2)O3-xBa(RE2/3W1/3)O3 (RE=Sm, Dy, Y, Yb) solid solutions
    Bian, Jianjiang
    Wu, Jiayin
    Ubic, Rick
    Karthik, C.
    Wu, Y.
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2015, 35 (05) : 1431 - 1439
  • [4] Significant enhancement in quality factor of Zn2TiO4 with Cu-substitution
    Butee, Sandeep
    Kulkarni, Ajit R.
    Prakash, Om
    Aiyar, R. P. R. C.
    Wattamwar, Ishan
    Bais, Durgesh
    Sudheendran, K.
    Raju, K. C. James
    [J]. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2011, 176 (07): : 567 - 572
  • [5] Microwave Dielectric Ceramics Li2MO4-TiO2 (M=Mo, W) with Low Sintering Temperatures
    Guo, Jing
    Zhou, Di
    Zou, Shen-Li
    Wang, Hong
    Pang, Li-Xia
    Yao, Xi
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2014, 97 (06) : 1819 - 1822
  • [6] Microwave dielectric properties of Li2TiO3 ceramics doped with LiF for LTCC applications
    Hao, Yi-Zhou
    Yang, Hui
    Chen, Guo-Hua
    Zhang, Qi-Long
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 552 : 173 - 179
  • [7] LOW-FIRE BISMUTH-BASED DIELECTRIC CERAMICS FOR MICROWAVE USE
    KAGATA, H
    INOUE, T
    KATO, J
    KAMEYAMA, I
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1992, 31 (9B): : 3152 - 3155
  • [8] Synthesis and dielectric properties of tungsten-based complex perovskites
    Khalyavin, DD
    Han, JP
    Senos, AMR
    Mantas, PQ
    [J]. JOURNAL OF MATERIALS RESEARCH, 2003, 18 (11) : 2600 - 2607
  • [9] Microwave dielectric ceramics for resonators and filters in mobile phone networks
    Reaney, Ian M.
    Iddles, David
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2006, 89 (07) : 2063 - 2072
  • [10] Low loss dielectric materials for LTCC applications: a review
    Sebastian, M. T.
    Jantunen, H.
    [J]. INTERNATIONAL MATERIALS REVIEWS, 2008, 53 (02) : 57 - 90