Chemistry of M(allyl)3 (M = Rh, Ir) compounds:: structural characterization of tris(allyl)iridium complexes with phosphorus ligands

被引：22
|
作者：
John, KD
Salazar, KV
Scott, BL
Baker, RT
Sattelberger, AP
机构：
[1] Univ Calif Los Alamos Natl Lab, Los Alamos Catalysis Initiat Chem Sci & Technol D, Los Alamos, NM 87545 USA
[2] Univ Calif Los Alamos Natl Lab, Div Mat Sci & Technol, Los Alamos, NM 87545 USA
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 07期
关键词：
D O I：
10.1039/a910164k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
While addition of phosphorus ligands such as P(OPh)(3) to Rh(allyl)(3) gives monovalent Rh(allyl)L-2, the iridium analog gives stable mixed sigma/pi-tris(allyl) complexes, as evidenced by the structural characterization of mono-, bi-, and tri-dentate ligand complexes.
引用
收藏
页码：581 / 582
页数：2
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