Interphase Evolution of a Lithium-Ion/Oxygen Battery

被引：45
|
作者：
Elia, Giuseppe Antonio [1 ]
Bresser, Dominic [2 ,3 ,4 ]
Reiter, Jakub [5 ]
Oberhumer, Philipp [5 ]
Sun, Yang-Kook [6 ]
Scrosati, Bruno [7 ]
Passerini, Stefano [2 ,3 ]
Hassoun, Jusef [1 ,8 ]
机构：
[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy
[2] Helmholtz Inst Ulm, Electrochem 1, D-89081 Ulm, Germany
[3] Karlsruhe Inst Technol, D-76021 Karlsruhe, Germany
[4] CEA CNRS UJF, CEA Grenoble, UMR 5819, INAC SPRAM PCI, F-38054 Grenoble 9, France
[5] BMW Grp, D-80788 Munich, Germany
[6] Hanyang Univ, Dept Energy Engn, Seoul 133791, South Korea
[7] Elettrochim & Energia, I-00199 Rome, Italy
[8] Univ Ferrara, Dipartimento Sci Chim & Farmaceut, I-44121 Ferrara, Italy
来源：
ACS APPLIED MATERIALS & INTERFACES | 2015年 / 7卷 / 40期
关键词：
Li/O-2; lithium-ion battery; ionic liquid electrolyte; high efficiency; safety; LIQUID-BASED ELECTROLYTES; ION OXYGEN BATTERY; POLYMER ELECTROLYTE; AIR BATTERIES; LI-O-2; STABILITY; ANODE;
D O I：
10.1021/acsami.5b07414
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A novel lithium-ion/oxygen battery employing Pyr(14)FSI-LiTESI as the electrolyte and nanostructured LixSn-C as the anode is reported. The remarkable energy content of the oxygen cathode, the replacement of the lithium metal anode by a nanostructured stable lithium-alloying composite, and the concomitant use of nonflammable ionic liquid-based electrolyte result in a new and intrinsically safer energy storage system. The lithium-ion/oxygen battery delivers a stable capacity of 500 mAh g(-1) at a working voltage of 2.4 V with a low charge-discharge polarization. However, further characterization of this new system by electrochemical impedance spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy reveals the progressive decrease of the battery working voltage, because of the crossover of oxygen through the electrolyte and its direct reaction with the LixSn-C anode.
引用
收藏
页码：22638 / 22643
页数：6
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