The synthesis and crystal structure of unsubstituted 4,4-difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY)

被引：109

作者：

Tram, Kha ^{[1
]}

Yan, Hongbin ^{[1
]}

Jenkins, Hilary A. ^{[2
]}

Vassiliev, Serguei ^{[3
]}

Brucec, Doug ^{[3
]}

机构：

[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada

[2] McMaster Univ, Dept Chem, Hamilton, ON L8S 4L9, Canada

[3] Brock Univ, Dept Biol, St Catharines, ON L2S 3A1, Canada

来源：

DYES AND PIGMENTS | 2009年 / 82卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

BODIPY; Fluorescence; Absorbance; Crystal structure; Dipyrromethane; DYES; PYRROMETHENES; COMPLEXES; BORON; DI;

D O I：

10.1016/j.dyepig.2009.03.001

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The fully unsubstituted 4,4-difluoro-4-bora-3a.4a-diaza-s-indacene (BODIPY) was synthesized for the first time by oxidation of dipyrromethane followed by treatment with boron trifluoride diethyl etherate in the presence of a base. The compound was fully characterized and its X-ray crystal structure is reported. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：392 / 395

页数：4

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