The synthesis and crystal structure of unsubstituted 4,4-difluoro-4-bora-3a, 4a-diaza-s-indacene (BODIPY)

被引：105
作者：
Tram, Kha [1 ]
Yan, Hongbin [1 ]
Jenkins, Hilary A. [2 ]
Vassiliev, Serguei [3 ]
Brucec, Doug [3 ]
机构：
[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
[2] McMaster Univ, Dept Chem, Hamilton, ON L8S 4L9, Canada
[3] Brock Univ, Dept Biol, St Catharines, ON L2S 3A1, Canada
来源：
DYES AND PIGMENTS | 2009年 / 82卷 / 03期
基金：
加拿大自然科学与工程研究理事会;
关键词：
BODIPY; Fluorescence; Absorbance; Crystal structure; Dipyrromethane; DYES; PYRROMETHENES; COMPLEXES; BORON; DI;
D O I：
10.1016/j.dyepig.2009.03.001
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The fully unsubstituted 4,4-difluoro-4-bora-3a.4a-diaza-s-indacene (BODIPY) was synthesized for the first time by oxidation of dipyrromethane followed by treatment with boron trifluoride diethyl etherate in the presence of a base. The compound was fully characterized and its X-ray crystal structure is reported. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：392 / 395
页数：4
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