Synthesis of quinoxalines using Gum Arabic as a nontoxic metal-free biocatalyst at room temperature in aqueous media

被引：11

作者：

Fazeli-Attar, Seyede Azita ^{[1
]}

Mirjalili, Bi Bi Fatemeh ^{[1
]}

机构：

[1] Yazd Univ, Coll Sci, Dept Chem, POB 89195-741, Yazd, Iran

来源：

ENVIRONMENTAL CHEMISTRY LETTERS | 2018年 / 16卷 / 02期

关键词：

Gum Arabic; 1,2-Diamines; 1,2-Diketones; Quinoxalines; Biocatalyst; EFFICIENT SYNTHESIS; CATALYZED SYNTHESIS; REUSABLE CATALYST; DERIVATIVES; NANOPARTICLES; FRACTIONATION; CONDENSATION; CHLORIDE;

D O I：

10.1007/s10311-017-0677-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the present study, Gum Arabic was used as a metal-free biocatalyst in the synthesis of quinoxaline derivatives through condensation of 1,2-diamines and 1,2-dicarbonyl compounds at room temperature under aqueous media. The advantages of the present protocol included the appropriate reaction times, high yields, and environmental friendliness. The structure of products was approved by FT-IR and H-1-NMR spectroscopy.

引用

页码：671 / 676

页数：6

共 40 条

[1]

Abu-Hashem, 2015, AM J ORG CHEM, V5, P14, DOI [10.5923/j.ajoc.20150501.03, DOI 10.5923/J.AJOC.20150501.03]

[2] Zirconium(IV) chloride as versatile catalyst for the expeditious synthesis of quinoxalines and pyrido[2,3-b]pyrazines under ambient conditions [J].

Aghapoor, Kioumars ;

Darabi, Hossein Reza ;

Mohsenzadeh, Farshid ;

Balavar, Yadollah ;

Daneshyar, Hesam .

TRANSITION METAL CHEMISTRY, 2010, 35 (01) :49-53

[3] NANO SbCl5SiO2 AN EFFICIENT CATALYST FOR THE SYNTHESIS OF QUINOXALINE DERIVATIVES AT ROOM TEMPERATURE UNDER SOLVENTLESS CONDITION [J].

Bamoniri, Abdolhamid ;

Mirjalili, Bibi Fatemeh ;

Karbasizadeh, Hassan .

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2015, 60 (01) :2851-2856

[4] Cyclodextrin conjugated magnetic colloidal nanoparticles as a nanocarrier for targeted anticancer drug delivery [J].

Banerjee, Shashwat S. ;

Chen, Dong-Hwang .

NANOTECHNOLOGY, 2008, 19 (26)

[5] Heterogeneous SnCl2/SiO2 versus Homogeneous SnCl2 Acid Catalysis in the Benzo[N,N]-heterocyclic Condensation [J].

Darabi, Hossein Reza ;

Aghapoor, Kioumars ;

Mohsenzadeh, Farshid ;

Jalali, Mohammad Reza ;

Talebian, Shiva ;

Ebadi-Nia, Leila ;

Khatamifar, Ehsan ;

Aghaee, Ali .

BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (01) :213-218

[6]

Fahimi N, 2016, IRAN J CATAL, V6, P161

[7] Superabsorbent hydrogel composed of covalently crosslinked gum arabic with fast swelling dynamics [J].

Favaro, Silvia L. ;

de Oliveira, Fernando ;

Reis, Adriano V. ;

Guilherme, Marcos R. ;

Muniz, Edvani C. ;

Tambourgi, Elias B. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (03) :1500-1506

[8] Designing of silver nanoparticles in gum arabic based semi-IPN hydrogel [J].

Gils, Palapparambil Sunny ;

Ray, Debajyoti ;

Sahoo, Prafulla Kumar .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2010, 46 (02) :237-244

[9] Zn[(L)proline]: A powerful catalyst for the very fast synthesis of quinoxaline derivatives at room temperature [J].

Heravi, Majid M. ;

Tehrani, Maryam H. ;

Bakhtiari, Khadijeh ;

Oskooie, Hossein A. .

CATALYSIS COMMUNICATIONS, 2007, 8 (09) :1341-1344

[10] On Water:: A practical and efficient synthesis of quinoxaline derivatives catalyzed by CuSO4 • 5H2O [J].

Heravi, Majid M. ;

Taheri, Shima ;

Bakhtiari, Khadijeh ;

Oskooie, Hossein A. .

CATALYSIS COMMUNICATIONS, 2007, 8 (02) :211-214

← 1 2 3 4 →