Rapid high conversion of high free fatty acid feedstock into biodiesel using continuous flow vortex fluidics

被引:13
作者
Britton, Joshua [1 ]
Raston, Colin L. [1 ]
机构
[1] Flinders Univ S Australia, Bedford Pk, SA 5042, Australia
基金
澳大利亚研究理事会;
关键词
WASTE COOKING OIL; DYNAMIC THIN-FILMS; L. SEED OIL; BIOFUELS PRODUCTION; JATROPHA-CURCAS; VEGETABLE-OILS; TRANSESTERIFICATION; FUEL; ESTERIFICATION; SYSTEM;
D O I
10.1039/c4ra14909b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Conversion of high free fatty acid (FFA) feedstock (94.4%) to biodiesel with undetectable FFA content is effective using room temperature vortex fluidic flow chemistry, with the conversion taking < 1 minute residence time, using dramatically less methanol and acid catalyst compared to other processes. Optimum conditions are 1 : 6 volumetric ratio of oil feedstock to methanol and 0.2 molar equivalents of H2SO4 catalyst loading, for a combined flow rate of 3.50 mL min(-1) in a 17.7 mm internal diameter tube rotating at 7500 rpm. This work furthers the viability of using high FFA content feedstocks for biodiesel production.
引用
收藏
页码:2276 / 2280
页数:5
相关论文
共 52 条
[1]   Biofuels versus food production: Does biofuels production increase food prices? [J].
Ajanovic, Amela .
ENERGY, 2011, 36 (04) :2070-2076
[2]   Production of biodiesel using high free fatty acid feedstocks [J].
Atadashi, I. M. ;
Aroua, M. K. ;
Aziz, A. R. Abdul ;
Sulaiman, N. M. N. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (05) :3275-3285
[3]   High quality biodiesel and its diesel engine application: A review [J].
Atadashi, I. M. ;
Aroua, M. K. ;
Aziz, A. Abdul .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2010, 14 (07) :1999-2008
[4]   Continuous-flow preparation of biodiesel using microwave heating [J].
Barnard, T. Michael ;
Leadbeater, Nicholas E. ;
Boucher, Matthew B. ;
Stencel, Lauren M. ;
Wilhite, Benjamin A. .
ENERGY & FUELS, 2007, 21 (03) :1777-1781
[5]   Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids [J].
Berchmans, Hanny Johanes ;
Hirata, Shizuko .
BIORESOURCE TECHNOLOGY, 2008, 99 (06) :1716-1721
[6]   A kinetic study of the esterification of free fatty acids (FFA) in sunflower oil [J].
Berrios, M. ;
Siles, J. ;
Martin, M. A. ;
Martin, A. .
FUEL, 2007, 86 (15) :2383-2388
[7]   Pilot Scale Two-phase Continuous Flow Biodiesel Production via Novel Laminar Flow Reactor-Separator [J].
Boucher, Matthew B. ;
Weed, Clifford ;
Leadbeater, Nicholas E. ;
Wilhite, Benjamin A. ;
Stuart, James D. ;
Parnas, Richard S. .
ENERGY & FUELS, 2009, 23 (5-6) :2750-2756
[8]  
Britton J., 2014, UNPUB
[9]   Continuous flow vortex fluidic production of biodiesel [J].
Britton, Joshua ;
Raston, Colin L. .
RSC ADVANCES, 2014, 4 (91) :49850-49854
[10]   Continuous production of biodiesel via transesterification from vegetable oils in supercritical methanol [J].
Bunyakiat, K ;
Makmee, S ;
Sawangkeaw, R ;
Ngamprasertsith, S .
ENERGY & FUELS, 2006, 20 (02) :812-817