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One-Step Synthesis of Unsymmetrical N-Alkyl-N′-aryl Perylene Diimides
被引:32
作者:
Robb, Maxwell J.
Newton, Brandon
Fors, Brett P.
Hawker, Craig J.
[1
]
机构:
[1] Univ Calif Santa Barbara, Dept Mat, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
基金:
美国国家科学基金会;
关键词:
ELECTRON-TRANSFER;
ENERGY-TRANSFER;
FLUORESCENT;
DYAD;
OLIGOTHIOPHENE;
D O I:
10.1021/jo500945k
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
An efficient and facile protocol for the synthesis of unsymmetrical N-alkyl-N'-aryl perylene diimides is reported that circumvents the need for multiple reaction steps. A number of unsymmetrical perylene diimides containing a solubilizing swallowtail alkyl group and a variety of substituted aryl groups can be prepared in a single step from a simple mixture of amines.
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页码:6360 / 6365
页数:6
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