Synthesis of beta-cyclodextrin-grafted-alginate and its application for removing methylene blue from water solution

被引:33
|
作者
Yang, Ji-sheng [1 ]
Han, Su-ya [1 ]
Yang, Li [1 ]
Zheng, Hai-cheng [1 ]
机构
[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
关键词
beta-cyclodextrin; alginate; hydrogel; methylene blue; SODIUM ALGINATE; PHOTOCATALYTIC OXIDATION; CHITOSAN; ENCAPSULATION; DEGRADATION; SOLUBILITY; COMPLEXES; BEHAVIOR; FILMS;
D O I
10.1002/jctb.4612
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
BACKGROUND: Beta-cyclodextrin (beta-CD) has a hydrophilic exterior and a hydrophobic internal cavity which gives it the ability to form a host-guest complex. Sodium alginate (NaAlg) is a natural polysaccharide which can form a hydrogel in the presence of divalent cations. RESULTS: The degree of substitution (DS) of the resulting beta-CD grafted alginate was 12%. The adsorption ratio of beta-CD to methylene blue (MB) was close to 2: 1 which agreed with the theoretical value. The inclusion property of the Alg-beta-CD/MB-Ca hydrogel was excellent and stable. The hydrogel could be disintegrated easily with the aid of Na2CO3, and the Alg-beta-CD sol obtained could be reused. CONCLUSION: This study indicated that the method of aggregation-disintegration of the prepared hydrogel used to adsorb MB from water was effective and could be reused. (C) 2014 Society of Chemical Industry
引用
收藏
页码:618 / 623
页数:6
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