Synthesis of beta-cyclodextrin-grafted-alginate and its application for removing methylene blue from water solution

被引：33

作者：

Yang, Ji-sheng ^{[1
]}

Han, Su-ya ^{[1
]}

Yang, Li ^{[1
]}

Zheng, Hai-cheng ^{[1
]}

机构：

[1] Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

来源：

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 2016年 / 91卷 / 03期

关键词：

beta-cyclodextrin; alginate; hydrogel; methylene blue; SODIUM ALGINATE; PHOTOCATALYTIC OXIDATION; CHITOSAN; ENCAPSULATION; DEGRADATION; SOLUBILITY; COMPLEXES; BEHAVIOR; FILMS;

D O I：

10.1002/jctb.4612

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

BACKGROUND: Beta-cyclodextrin (beta-CD) has a hydrophilic exterior and a hydrophobic internal cavity which gives it the ability to form a host-guest complex. Sodium alginate (NaAlg) is a natural polysaccharide which can form a hydrogel in the presence of divalent cations. RESULTS: The degree of substitution (DS) of the resulting beta-CD grafted alginate was 12%. The adsorption ratio of beta-CD to methylene blue (MB) was close to 2: 1 which agreed with the theoretical value. The inclusion property of the Alg-beta-CD/MB-Ca hydrogel was excellent and stable. The hydrogel could be disintegrated easily with the aid of Na2CO3, and the Alg-beta-CD sol obtained could be reused. CONCLUSION: This study indicated that the method of aggregation-disintegration of the prepared hydrogel used to adsorb MB from water was effective and could be reused. (C) 2014 Society of Chemical Industry

引用

页码：618 / 623

页数：6

共 32 条

[1] Synthesis, characterization and bending behavior of electroresponsive sodium alginate/poly(acrylic acid) interpenetrating network films under an electric field stimulus [J].

Bekin, Seda ;

Sarmad, Shokat ;

Gurkan, Koray ;

Keceli, Gonul ;

Gurdag, Gulten .

SENSORS AND ACTUATORS B-CHEMICAL, 2014, 202 :878-892

[2] Inclusion complexes of β-cyclodextrin with chlorogenic acids (CHAs) from crude and purified aqueous extracts of green Robusta coffee beans (Coffea canephora L.) [J].

Budryn, Grazyna ;

Nebesny, Ewa ;

Palecz, Bartlomiej ;

Rachwal-Rosiak, Danuta ;

Hodurek, Pawel ;

Miskiewicz, Karolina ;

Oracz, Joanna ;

Zyzelewicz, Dorota .

FOOD RESEARCH INTERNATIONAL, 2014, 61 :202-213

[3]

Chen Xiao-qing, 2007, Journal of Central South University (Science and Technology), V38, P112

[4] Synthesis, characterization and anti-tubercular activity of ferrocenyl hydrazones and their β-cyclodextrin conjugates [J].

Dandawate, Prasad ;

Vemuri, Kiranmayi ;

Khan, Ejazuddin M. ;

Sritharan, Manjula ;

Padhye, Subhash .

CARBOHYDRATE POLYMERS, 2014, 108 :135-144

[5] REMOVAL OF METHYLENE BLUE FROM AQUEOUS SOLUTION USING GHASSOUL, A LOW-COST ADSORBENT [J].

Elass, K. ;

Laachach, A. ;

Alaoui, A. ;

Azzi, M. .

APPLIED ECOLOGY AND ENVIRONMENTAL RESEARCH, 2010, 8 (02) :153-163

[6] Adsorption of dyestuff from aqueous solutions through oxalic acid-modified swede rape straw: Adsorption process and disposal methodology of depleted bioadsorbents [J].

Feng, Yanfang ;

Dionysiou, Dionysios D. ;

Wu, Yonghong ;

Zhou, Hui ;

Xue, Lihong ;

He, Shiying ;

Yang, Linzhang .

BIORESOURCE TECHNOLOGY, 2013, 138 :191-197

[7] Mononuclear rearrangements of heterocycles in water/β-CD:: information on the real site of reaction from structural modifications of substrates and from proton concentration dependence of the reactivity [J].

Guernelli, Susanna ;

Lo Meo, Paolo ;

Morganti, Stefano ;

Noto, Renato ;

Spinelli, Domenico .

TETRAHEDRON, 2007, 63 (41) :10260-10268

[8] Cyclodextrin-based aggregates and characterization by microscopy [J].

He, Yifeng ;

Fu, Pei ;

Shen, Xinghai ;

Gao, Hongcheng .

MICRON, 2008, 39 (05) :495-516

[9] Dehydration of ethanol through blend membranes of chitosan and sodium alginate by pervaporation [J].

Kanti, P ;

Srigowri, K ;

Madhuri, J ;

Smitha, B ;

Sridhar, S .

SEPARATION AND PURIFICATION TECHNOLOGY, 2004, 40 (03) :259-266

[10] Probing aggregation and encapsulation behaviour of structurally akin ketocyanine dyes in aqueous media containing β-cyclodextrin: A spectroscopic analysis [J].

Kedia, Niraja ;

Sarkar, Amrita ;

Purkayastha, Pradipta ;

Bagchi, Sanjib .

JOURNAL OF MOLECULAR LIQUIDS, 2014, 195 :259-266

← 1 2 3 4 →