A facile conversion of thio- and selenophosphoric acids and their derivatives into fluoridates by means of reaction with silver fluoride

被引：22

作者：

Chworos, A ^{[1
]}

Wozniak, LA ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, Dept Bioorgan Chem, PL-90363 Lodz, Poland

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 52期

关键词：

halogenation (fluorination); oxygenation; phosphorus compounds; thiophosphorus compounds;

D O I：

10.1016/S0040-4039(99)01977-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of numerous thio- or selenophosphorus acids with aqueous silver fluoride in CHCl3 at room temperature results in clean formation of the corresponding fluoridates. Analogous results were obtained with other phosphorothio (seleno)ates such as esters, amidates, or halides, (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：9337 / 9340

页数：4

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