KINETIC FEATURES OF THE REDOX REACTION BETWEEN RUTHENIUM(III) CHLORIDE AND SODIUM TETRAHYDROBORATE

被引：0

作者：

Dasgupta, M. ^{[1
]}

Mahanti, M. K. ^{[1
]}

机构：

[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India

来源：

OXIDATION COMMUNICATIONS | 2014年 / 37卷 / 01期

关键词：

kinetics; ruthenium(III); sodium tetrahydroborate; AQUEOUS-SOLUTION; NICKEL BORIDE; COMPLEXES; BOROHYDRIDE; HYDROGENATION; OXIDATION; CATALYSTS; MECHANISM; PRODUCTS; COBALT;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the redox reaction between sodium tetrahydroborate and ruthenium(111) ions in aqueous acidic medium has been studied. The effects of changes in the concentrations of the reactants (RuCl3 center dot 3H(2)O and BH4-) and variations in the pH of the medium have been highlighted. A plausible mechanism for the reaction has been suggested.

引用

页码：108 / 111

页数：4

共 31 条

[11] Kinetic and mechanistic studies of oxidation of chloramphenicol by sodium metaperiodate using Rh(III)-chloride as homogeneous catalyst [J].

Pradhan, Ranju ;

Srivastava, Jaya ;

Bala, Ritu Swamini ;

Yadav, Rupam ;

Rahmani, Shahla ;

Singh, Ashok Kumar .

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2018, 57 (04) :477-484

[12] Kinetics and Mechanism of Redox Reaction between Tetrachloroaurate(III) Ions and Hydrazine [J].

Streszewski, Bartlomiej ;

Jaworski, Wiktor ;

Szacilowski, Konrad ;

Paclawski, Krzysztof .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2014, 46 (06) :328-337

[13] Ruthenium(III) chloride catalyzed oxidation reaction of cyclohexane and cyclohexanol in ionic liquid [J].

Tang, WM ;

Li, CJ .

ACTA CHIMICA SINICA, 2004, 62 (07) :742-744

[14] The mechanism of the reaction between Au(III) and PADA in sodium dodecylsulphate [J].

Aydinoglu, Sabriye ;

Biver, Tarita ;

Secco, Fernando ;

Venturini, Marcella .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2016, 498 :81-87

[15] Kinetic Studies on Ruthenium(III) Chloride-Catalyzed Oxidation of Benzyl and Homobenzyl Alcohols Using Cerium(IV) Sulfate under Acidic Medium [J].

Yadav, Suresh C. ;

Srivastav, Shalini ;

Singh, Alok K. ;

Pandey, Vijay ;

Tandon, Praveen K. ;

Chandra, Ajeet .

CHEMISTRYSELECT, 2024, 9 (25)

[16] Formation of thiocyanato bridged dinuclear ruthenium(III) complex ion by the reaction between thiocyanatopentaammineruthenium(III) and aquapentaammine-ruthenium(III) complex ions in aqueous medium [J].

Chakravarty, B ;

Bisai, S .

JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2003, 80 (08) :744-746

[17] RECENT TRENDS IN KINETICS IN ANALYTICAL CHEMISTRY AND KINETIC METHOD FOR DETERMINATION OF RUTHENIUM (III) USING ANILINE BLUE-ACIDIC CHLORITE REACTION [J].

Jonnalagadda, Sreekanth B. ;

Pare, Brijesh .

ANALYTICAL LETTERS, 2011, 44 (11) :1868-1878

[18] SPECTRAL CHARACTERISTICS AND KINETIC FEATURES OF REDOX REACTIONS OF NICKEL(II) AND NICKEL(III) COMPLEXES WITH DIOXOTETRAAZA MACROCYCLIC LIGANDS [J].

GAVRISH, SP ;

LAMPEKA, YD .

JOURNAL OF COORDINATION CHEMISTRY, 1991, 24 (04) :351-362

[19] KINETICS AND MECHANISM OF THE REDOX REACTION BETWEEN Pt(IV) CHLORIDE COMPLEX IONS AND SODIUM THIOSULFATE IN AQUEOUS SOLUTION. PART I: ACIDIC SOLUTION [J].

Paclawski, K. ;

Piwowonska, J. .

ARCHIVES OF METALLURGY AND MATERIALS, 2014, 59 (04) :1413-1420

[20] Kinetics and mechanism of the redox reaction between malachite green and iron(III) in aqueous and micellar media [J].

Hameed, Salem A. ;

Ewais, Hassan A. .

TRANSITION METAL CHEMISTRY, 2014, 39 (02) :199-204

← 1 2 3 4 →