Natural Sugar: A Green Assistance To Efficiently Exfoliate Inorganic Layered Nanomaterials

被引：13

作者：

Chen, Kai ^{[1
]}

Zhang, Wentao ^{[1
]}

Pan, Xinjie ^{[2
]}

Huang, Lunjie ^{[1
]}

Wang, Jing ^{[1
]}

Yang, Qingfeng ^{[1
]}

Hu, Na ^{[3
]}

Suo, Yourui ^{[3
]}

Zhang, Daohong ^{[1
]}

Wang, Jianlong ^{[1
]}

机构：

[1] Northwest A&F Univ, Coll Food Sci & Engn, Yangling 712100, Shaanxi, Peoples R China

[2] Northwest A&F Univ, Coll Chem & Pharm, Yangling 712100, Shaanxi, Peoples R China

[3] Chinese Acad Sci, Northwest Inst Plateau Biol, Qinghai Key Lab Qinghai Tibet Plateau Biol Resour, Xining 810008, Qinghai, Peoples R China

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 09期

基金：

中国国家自然科学基金;

关键词：

MOS2; NANOSHEETS; MOLYBDENUM-DISULFIDE; GRAPHENE NANOSHEETS; HIGH-QUALITY; DISPERSIONS; NANODOTS; CRYSTALS; CAPACITY; FRET; FOOD;

D O I：

10.1021/acs.inorgchem.8b00525

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have demonstrated that natural sugars can efficiently exfoliate inorganic layered nanomaterials with direct stirring. The representative transition-metal dichalcogenides (MoS2 and WS2), transition-metal oxide (MoO3), and graphene were explored, and the formation of ultrathin nanosheets was verified. Glucose and MoS2 selected each other as the perfect partner with superior exfoliation and excellent properties. The obtained inorganic layered nanosheets possess favorable stability and dispersity, which renders it suitable for direct homogeneous liquid applications, such as catalytic activities and sensors. With a high-throughput and green process, the sugar-assisted method may offer new ideas for inorganic layered nanomaterials synthesis and applications in a more ecofriendly way.

引用

页码：5560 / 5566

页数：7

共 41 条

[1] Effective Liquid-Phase Exfoliation and Sodium Ion Battery Application of MoS2 Nanosheets [J].

Bang, Gyeong Sook ;

Nam, Kwan Woo ;

Kim, Jong Yun ;

Shin, Jongwoo ;

Choi, Jang Wook ;

Choi, Sung-Yool .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (10) :7084-7089

[2] Nanocomposite of MoS2 on ordered mesoporous carbon nanospheres: A highly active catalyst for electrochemical hydrogen evolution [J].

Bian, Xiaojun ;

Zhu, Jie ;

Liao, Lei ;

Scanlon, Micheal D. ;

Ge, Peiyu ;

Ji, Chang ;

Girault, Hubert H. ;

Liu, Baohong .

ELECTROCHEMISTRY COMMUNICATIONS, 2012, 22 :128-132

[3] Label-free fluorescence aptasensor for sensitive determination ofbisphenol S by the salt-adjusted FRET between CQDs and MoS2 [J].

Chen, Kai ;

Zhang, Wentao ;

Zhang, Yuhuan ;

Huang, Lunjie ;

Wang, Rong ;

Yue, Xiaoyue ;

Zhu, Wenxin ;

Zhang, Daohong ;

Zhang, Xu ;

Zhang, Ying ;

Wang, Jianlong .

SENSORS AND ACTUATORS B-CHEMICAL, 2018, 259 :717-724

[4] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].

Coleman, Jonathan N. ;

Lotya, Mustafa ;

O'Neill, Arlene ;

Bergin, Shane D. ;

King, Paul J. ;

Khan, Umar ;

Young, Karen ;

Gaucher, Alexandre ;

De, Sukanta ;

Smith, Ronan J. ;

Shvets, Igor V. ;

Arora, Sunil K. ;

Stanton, George ;

Kim, Hye-Young ;

Lee, Kangho ;

Kim, Gyu Tae ;

Duesberg, Georg S. ;

Hallam, Toby ;

Boland, John J. ;

Wang, Jing Jing ;

Donegan, John F. ;

Grunlan, Jaime C. ;

Moriarty, Gregory ;

Shmeliov, Aleksey ;

Nicholls, Rebecca J. ;

Perkins, James M. ;

Grieveson, Eleanor M. ;

Theuwissen, Koenraad ;

McComb, David W. ;

Nellist, Peter D. ;

Nicolosi, Valeria .

SCIENCE, 2011, 331 (6017) :568-571

[5] MoS2 Nanoparticles Decorating Titanate-Nanotube Surfaces: Combined Microscopy, Spectroscopy, and Catalytic Studies [J].

Cravanzola, Sara ;

Muscuso, Lucia ;

Cesano, Federico ;

Agostini, Giovanni ;

Damin, Alessandro ;

Scarano, Domenica ;

Zecchina, Adriano .

LANGMUIR, 2015, 31 (19) :5469-5478

[6] Controlled Exfoliation of MoS2 Crystals into Trilayer Nanosheets [J].

Fan, Xiaobin ;

Xu, Pengtao ;

Li, Yuguang C. ;

Zhou, Dekai ;

Sun, Yifan ;

Nguyen, Minh An T. ;

Terrones, Mauricio ;

Mallouk, Thomas E. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (15) :5143-5149

[7] Liquid-exfoliated MoS2 by chitosan and enhanced mechanical and thermal properties of chitosan/MoS2 composites [J].

Feng, Xiaming ;

Wang, Xin ;

Xing, Weiyi ;

Zhou, Keqing ;

Song, Lei ;

Hu, Yuan .

COMPOSITES SCIENCE AND TECHNOLOGY, 2014, 93 :76-82

[8] MoS2 Quantum Dot-Interspersed Exfoliated MoS2 Nanosheets [J].

Gopalakrishnan, Deepesh ;

Damien, Dijo ;

Shaijumon, Manikoth M. .

ACS NANO, 2014, 8 (05) :5297-5303

[9] Electrostatic-Driven Exfoliation and Hybridization of 2D Nanomaterials [J].

Guan, Guijian ;

Xia, Jing ;

Liu, Shuhua ;

Cheng, Yuan ;

Bai, Shiqiang ;

Tee, Si Yin ;

Zhang, Yong-Wei ;

Han, Ming-Yong .

ADVANCED MATERIALS, 2017, 29 (32)

[10] Protein Induces Layer-by-Layer Exfoliation of Transition Metal Dichalcogenides [J].

Guan, Guijian ;

Zhang, Shuangyuan ;

Liu, Shuhua ;

Cai, Yongqing ;

Low, Michelle ;

Teng, Choon Peng ;

Phang, In Yee ;

Cheng, Yuan ;

Duei, Koh Leng ;

Srinivasan, Bharathi Madurai ;

Zheng, Yuangang ;

Zhang, Yong-Wei ;

Han, Ming-Yong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (19) :6152-6155

← 1 2 3 4 5 →