The progress in the chemistry of N-acyliminium ions and their use in stereoselective organic synthesis

被引：25

作者：

Vinogradov, Maxim G. ^{[1
]}

Turova, Olga V. ^{[2
]}

Zlotin, Sergei G. ^{[2
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Lab Fine Organ Synth, ZIOC RAS, Leninsky Prosp 47, Moscow 119991, Russia

[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Lab Fine Organ Synth, Leninsky Prosp 47, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL REVIEWS | 2017年 / 86卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

IN-SITU GENERATION; DIASTEREOSELECTIVE CONSTRUCTION; MANNICH REACTIONS; FACILE SYNTHESIS; CYCLIZATION; ACID; THIOUREA; INDOLES; ACCESS; DERIVATIVES;

D O I：

10.1070/RCR4628

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The review summarizes data published in the last decade on the reactions of organic compounds involving N-acyliminium ions, including intramolecular arylation (cyclization), cross-coupling with nucleophiles and some other transformations to form new carbon carbon and carbon-heteroatom bonds. The stereo-and enantioselective versions of these reactions using chiral auxiliaries and asymmetric catalysts (organocatalysts) are considered. Examples of application of N-acyliminium ions for the synthesis of natural compounds and their analogues are presented. The bibliography includes 100 references.

引用

页码：1 / 17

页数：17

共 100 条

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