Stepwise assembly of multidimensional Al-Pb based coordination polymers

被引：2

作者：

Wang, San-Tai ^{[1
,2
]}

Fang, Wei-Hui ^{[2
]}

Zhang, Shu-Hua ^{[1
]}

机构：

[1] Guilin Univ Technol, Coll Chem & Bioengn, Guangxi Key Lab Electrochem & Magnetochem Funct M, Collaborat Innovat Ctr Explorat Hidden Nonferrous, Guilin 541004, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2021年 / 293卷

基金：

中国国家自然科学基金;

关键词：

Clusters; Main group elements; Al-Pb compounds; Stepwise assembly; Aluminum oxo clusters;

D O I：

10.1016/j.jssc.2020.121804

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of the main group elements has always been attractive. Present herein is a stepwise assembly approach toward multidimensional Al-Pb based crystalline compounds. [Al2Pb3(L)(2)(HL)(2)(mu(3)-OH)(2)](2)center dot 2Hdma center dot 2H(2)O center dot 2Cl (AlOC-48) and [AlPb2(L)(2)(mu(3)-OH)]center dot 3H(2)O (AlOC-49) (H3L = 2,3-dihydroxybenzoic acid, Cat = catechol and dma = dimethylamine) represent the first examples of multidimensional Al-Pb based compounds. They are assembled through [Al-4(L)(4)(Cat)(2)]](4-) (Al-4, AlOC-13) polyanions and Pb ions. During the process of coordination assembly, metal site substitution occurs on the Al-4 precursors and transform into Al2Pb2 unit. AlOC-48 and AlOC-49 are two-dimensional and three-dimensional frameworks based on Al2Pb2 clusters. Moreover, the optical band gap and photocurrent response of these two compounds are studied.

引用

页数：5

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