MOFs as Adsorbents for Low Temperature Heating and Cooling Applications

被引：400

作者：

Henninger, Stefan K. ^{[1
]}

Habib, Hesham A. ^{[2
]}

Janiak, Christoph ^{[2
]}

机构：

[1] Fraunhofer Inst Solare Energiesyst ISE, D-79110 Freiburg, Germany

[2] Univ Freiburg, Inst Anorgan & Analyt Chem, D-79104 Freiburg, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 08期

关键词：

METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; HYDROGEN STORAGE; WATER-ADSORPTION; CHEMISTRY; NETWORKS; SYSTEMS; PUMP;

D O I：

10.1021/ja808444z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 3D metal-organic framework (MOF)(3)-{[Ni(3)(mu(3)-btc)(2)(mu(4)-btre)(2)(mu-H(2)O)(2)]center dot similar to 22H(2)O} is found to be a reversibly dehydratable-hydratable water-stable MOF material with a Large Loading spread of 210 g/kg as a candidate for solid adsorbents in heat transformation cycles for refrigeration, heat pumping, and heat storage.

引用

页码：2776 / +

页数：3