Resonant photoemission spectroscopy study of electronic structure of V2O5

被引：23
作者：
Wu, Qi-Hui [1 ]
Thissen, A.
Jaegermann, W.
Schuez, M.
Schmidt, P. C.
机构：
[1] Xiamen Univ, Dept Phys, Xiamen 361005, Peoples R China
[2] Xiamen Univ, Semicond Photon Res Ctr, Xiamen 361005, Peoples R China
[3] Tech Univ Darmstadt, Dept Mat Sci, Surface Sci Inst, D-64283 Darmstadt, Germany
[4] Tech Univ Darmstadt, Dept Chem, Inst Phys Chem, D-64283 Darmstadt, Germany
来源：
CHEMICAL PHYSICS LETTERS | 2006年 / 430卷 / 4-6期
关键词：
D O I：
10.1016/j.cplett.2006.08.071
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electronic structure of V2O5 has been studied by resonant photoemission spectroscopy (RPES) and band structure calculation. The RPES data showed that the valence band (VB) of V2O5 is formed by strong hybridization of O2p and V3d states, the contribution from V3d state is predominant in the high binding energy (BE) region of the VB. The approximate charge distributions of O and V ions in V2O5 are calculated for the first time as V23+O51.2- from the RPES data. (c) 2006 Elsevier B.V. All rights reserved.
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页码：309 / 313
页数：5
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