Metal-free Reduction of Nitro Aromatics to Amines with B2(OH)4/H2O

被引：57

作者：

Chen, Danyi ^{[1
]}

Zhou, Yanmei ^{[1
]}

Zhou, Haifeng ^{[1
]}

Liu, Sensheng ^{[1
]}

Liu, Qixing ^{[1
]}

Zhang, Kaili ^{[1
]}

Uozumi, Yasuhiro ^{[1
,2
]}

机构：

[1] China Three Gorges Univ, Coll Biol & Pharmaceut Sci, Res Ctr Green Pharmaceut Technol & Proc, Hubei Key Lab Nat Prod Res & Dev, Yichang 443002, Peoples R China

[2] Inst Mol Sci, Okazaki, Aichi 4448787, Japan

来源：

SYNLETT | 2018年 / 29卷 / 13期

基金：

中国国家自然科学基金;

关键词：

diboronic acid; nitro aromatics; amines; reduction; water; CATALYZED TRANSFER HYDROGENATION; ONE-POT SYNTHESIS; CHEMOSELECTIVE REDUCTION; SELECTIVE HYDROGENATION; NITROAROMATIC COMPOUNDS; REUSABLE CATALYST; DIBORONIC ACID; WATER; NITROARENES; ANILINES;

D O I：

10.1055/s-0037-1610086

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A metal-free reduction of nitro aromatics mediated by diboronic acid with water as both the hydrogen donor and solvent under mild conditions has been developed. A series of aromatic amines were obtained with good functional group tolerance and in good yields.

引用

页码：1765 / 1768

页数：4

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