(1,2-Dicyanoethylenedithiolato-κ2S,S′)(η5-pentamethylcyclopentadienyl)iridium(III)

被引：4

作者：

Ren, Chun-Xia ^{[1
]}

Ding, Yu-Qiang ^{[1
]}

机构：

[1] So Yangtze Univ, Sch Chem & Mat Engn, Wuxi 214122, Jiangsu, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷

关键词：

D O I：

10.1107/S160053680604459X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of the title complex, [Ir(C10H15)-(C4N2S2)], is composed of distinct [eta 5-Cp*Ir(mnt)] (Cp* is pentamethylcyclopentadienyl and mnt is 1,2-dicyanoethylene-dithiolate) molecules separated by normal van der Waals contacts. The asymmetric unit consists of two molecules. The Ir-III atom may be considered pentacoordinate since it is linked to a bidentate dithiolate ligand and a formally tridentate eta(5)-Cp* ligand. Ir - S distances range from 2.238 (3) to 2.246 (3) angstrom.

引用

页码：M249 / M250

页数：2

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