Microwave-assisted synthesis of rod-like CuO/TiO2 for high-efficiency photocatalytic hydrogen evolution

被引:57
作者
Yu, Yi-Hsien [1 ]
Chen, Ying-Pin [2 ]
Cheng, Zhengdong [1 ,3 ]
机构
[1] Texas A&M Univ, Dept Mat Sci & Engn, College Stn, TX 77843 USA
[2] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
[3] Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77843 USA
关键词
CuO; TiO2; rods; Microwave-assisted synthesis; Photocatalytic; Hydrogen evolution; TIO2; WATER; CUO; CATALYST; ARRAYS;
D O I
10.1016/j.ijhydene.2015.09.115
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CuO-deposited TiO2 rod composites were prepared through a microwave-assisted green method for high efficiency hydrogen evolution. The porous CuO/TiO2 rods with crystallinity and high specific surface (249.1 m(2)/g) area were obtained as-synthesized without calcination. Hydrogen yields were proved to be significantly improved with appropriate amount of CuO deposited onto TiO2 rods. The improved photocatalytic performance was attributed to the synergistic effects of high surface area, specific energy band structure, and enhanced light harvesting at the interface of CuO and porous TiO2 rods. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:15994 / 16000
页数:7
相关论文
共 27 条
  • [1] Microwave-Assisted Synthesis of Colloidal Inorganic Nanocrystals
    Baghbanzadeh, Mostafa
    Carbone, Luigi
    Cozzoli, P. Davide
    Kappe, C. Oliver
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (48) : 11312 - 11359
  • [2] Highly stable CuO incorporated TiO2 catalyst for photocatalytic hydrogen production from H2O
    Bandara, J
    Udawatta, CPK
    Rajapakse, CSK
    [J]. PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2005, 4 (11) : 857 - 861
  • [3] The role of CuO in promoting photocatalytic hydrogen production over TiO2
    Chen, Wan-Ting
    Jovic, Vedran
    Sun-Waterhouse, Dongxiao
    Idriss, Hicham
    Waterhouse, Geoffrey I. N.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (35) : 15036 - 15048
  • [4] TiO2/CdS composite hollow spheres with controlled synthesis of platinum on the internal wall for the efficient hydrogen evolution
    Cui, Xiaofeng
    Jiang, Guiyuan
    Zhu, Ming
    Zhao, Zhen
    Du, Luchao
    Weng, Yuxiang
    Xu, Chunming
    Zhang, Dekai
    Zhang, Quanlai
    Wei, Yuechang
    Duan, Aijun
    Liu, Jian
    Gao, Jinsen
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (22) : 9065 - 9073
  • [5] Hydrogen evolution reaction of low carbon steel electrode in hydrochloric acid as a source for hydrogen production
    El-Meligi, A. A.
    Ismail, N.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (01) : 91 - 97
  • [6] ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE
    FUJISHIMA, A
    HONDA, K
    [J]. NATURE, 1972, 238 (5358) : 37 - +
  • [7] Photodegradation of rhodamine B and methyl orange over one-dimensional TiO2 catalysts under simulated solar irradiation
    Guo, Changsheng
    Xu, Jian
    He, Yan
    Zhang, Yuan
    Wang, Yuqiu
    [J]. APPLIED SURFACE SCIENCE, 2011, 257 (08) : 3798 - 3803
  • [8] Synergistic Effect of CdSe Quantum Dot Sensitization and Nitrogen Doping of TiO2 Nanostructures for Photoelectrochemical Solar Hydrogen Generation
    Hensel, Jennifer
    Wang, Gongming
    Li, Yat
    Zhang, Jin Z.
    [J]. NANO LETTERS, 2010, 10 (02) : 478 - 483
  • [9] Fabricating CdS/BiVO4 and BiVO4/CdS heterostructured film photoelectrodes for photoelectrochemical applications
    Jiang, Jiangang
    Wang, Meng
    Li, Rong
    Ma, Lijing
    Guo, Liejin
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (29) : 13069 - 13076
  • [10] Photocatalytic hydrogen production over CuO and TiO2 nanoparticles mixture
    Kum, Jong Min
    Yoo, Seung Hwa
    Ali, Ghafar
    Cho, Sung Oh
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (31) : 13541 - 13546