Opening size optimization of metal matrix in rolling-pressed activated carbon air-cathode for microbial fuel cells

被引:66
作者
Li, Xiaojing [1 ]
Wang, Xin [1 ]
Zhang, Yueyong [1 ]
Ding, Ning [1 ]
Zhou, Qixing [1 ]
机构
[1] Nankai Univ, Coll Environm Sci & Engn, Tianjin Key Lab Environm Remediat & Pollut Contro, MOE Key Lab Pollut Proc & Environm Criteria, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
Microbial fuel cell; Activated carbon; Air-cathode; Stainless steel mesh; Electrochemical impedance spectrum; WASTE-WATER TREATMENT; MESH CURRENT COLLECTORS; ELECTRICITY-GENERATION; ENHANCED PERFORMANCE; POWER-GENERATION; CATALYST LAYER; PTFE; ELECTRODES; ANODES; BINDER;
D O I
10.1016/j.apenergy.2014.02.048
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Stainless steel mesh (SSM) with four opening sizes (20-80 M) were investigated as matrixes of activated carbon air-cathodes in microbial fuel cells (MFCs). The highest power density of 2151 +/- 109 mW m(-2) (at 5.54 +/- 0.14 A m(-2)) was obtained using 40 M, with a value 45% higher than 1485 +/- 18 mW m(-2) of 80 M. The trend of linear sweep voltammetries were in accordant with power output over a cathodic potential range from -0.2 to 0 V. The differences in performance were attributed to the internal resistances. Charge transfer resistance (R-ct) was the dominant internal resistance in most of air-cathodes, with the lowest value of 2 52 in 40 M. Density of metal mesh exhibited a more significant correlationship with maximum power densities (R-2 = 0.9222) compared to opening size (R-2 = 0.7068), demonstrated that the density of metal current collector was vital to the performance of cathodes. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:13 / 18
页数:6
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