Role of pre-organization around the azaphosphatrane catalyst's active site in the conversion of CO2 to cyclic carbonates

被引：17

作者：

Chatelet, Bastien ^{[1
]}

Jeanneau, Erwann ^{[2
]}

Dutasta, Jean-Pierre ^{[1
]}

Robert, Vincent ^{[3
]}

Martinez, Alexandre ^{[1
]}

Dufaud, Veronique ^{[4
]}

机构：

[1] UCBL, CNRS, Ecole Normale Super Lyon, Chim Lab, F-69364 Lyon, France

[2] Univ Lyon 1, Ctr Diffractometrie Henri Longchambon, F-69100 Villeurbanne, France

[3] Univ Strasbourg, UMR CNRS 7177, Inst Chim, Lab Chim Quant, F-67070 Strasbourg, France

[4] Univ Lyon 1, CNRS, Proc UMR 5265, Chim Lab, F-69616 Villeurbanne, France

来源：

CATALYSIS COMMUNICATIONS | 2014年 / 52卷

关键词：

Azaphosphatranes; Cyclic carbonates; CO2 chemical valorization; Homogeneous catalysis; Epoxides; ORGANIC CARBONATES; DIOXIDE; EPOXIDES; ACTIVATION; FIXATION; SOLVENTS;

D O I：

10.1016/j.catcom.2014.04.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Various N-substituted azaphosphatranes have been prepared and successfully applied to the synthesis of styrene carbonates from CO2 and epoxides. Enhancement of the catalytic properties of the azaphosphatrane was achieved upon pre-organization of the active site through hydrogen-bonding. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：26 / 30

页数：5

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