Dual-functional graphene/carbon nanotubes thick film: Bidirectional thermal dissipation and electromagnetic shielding

被引:78
作者
Jia, Hui [1 ,2 ]
Kong, Qing-Qiang [1 ,2 ]
Yang, Xiao [1 ,2 ]
Xie, Li-Jing [1 ]
Sun, Guo-Hua [1 ]
Liang, Lei-Lei [1 ,2 ]
Chen, Jing-Peng [1 ,2 ]
Liu, Dong [1 ,2 ]
Guo, Quan-Gui [1 ]
Chen, Cheng-Meng [1 ,3 ]
机构
[1] Chinese Acad Sci, Inst Coal Chem, CAS Key Lab Carbon Mat, Taiyuan 030001, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
Graphene/CNTs thick film; Molecular dynamics simulations; In-plane and through-plane thermal conductivity; High heat flux; Electromagnetic shielding; COMPOSITE FILMS; OXIDE-FILMS; CARBON NANOTUBE; CONDUCTIVITY; GRAPHITE; PAPER; GRAPHITIZATION;
D O I
10.1016/j.carbon.2020.09.017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Spacecraft materials are a key limiting factor for the rapid development of the aerospace exploration field. In an advanced spacecraft, superior multi-functional material with thermal management and electromagnetic shielding can ensure the normal operation of its equipment in space. Currently, graphene thin film can't satisfy a high heat flux and excellent through-plane thermal conduction. In this contribution, a full-carbon dual-functional graphene/carbon nanotubes (CNTs) thick film with high heat flux was successfully prepared, and the structure and composition evolution was investigated after hot-pressing carbonization and graphitization of 2800 degrees C, which indicates the existence of a compact defectsfree and high crystalline carbon structure. Molecular dynamics simulations further confirm the formation of C-C covalent bonds between graphene sheets and CNTs after 2800 degrees C graphitization, enhancing the phonons transfer in through-plane. Simultaneously, the axially adjacent graphene sheets are connected by the CNTs, which endow excellent thermal conductive properties. The in-plane and through-plane thermal diffusivity are as high as 1188.2 mm(2)/s and 8.0 mm(2)/s, respectively. Moreover, the electrical conductivity up to 1819.17 S/cm and EMI SE reach 75 dB in Ku-band. The results provide a bright prospect for spacecraft materials preparation and application. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页码:329 / 340
页数:12
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