Radiation reduction of dicarboxylatoimidazole platinum(II) complexes in the water-methanol system

被引：2

作者：

Kalecinska, E ^{[1
]}

Kalecinski, J ^{[1
]}

KudukJaworska, J ^{[1
]}

机构：

[1] POLISH ACAD SCI,W TRZEBIATOWSKI INST LOW TEMP & STRUCT RES,PL-50950 WROCLAW,POLAND

来源：

RADIATION PHYSICS AND CHEMISTRY | 1997年 / 50卷 / 04期

关键词：

D O I：

10.1016/S0969-806X(97)00054-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The radiation reduction of bis(1-ethylimidazole)tartratoplatinum(II) (EITPt(II)) complexes in methanol-water solutions have been examined. The yields of Pt(I) depend on the presence of O-2 in solution as well as the dose applied. The rate constants of e(s)(-) scavenging by EITPt(II) and cis(diammine-1,1-cyclogutanedicarboxylato)platinum(II) (CBDCAPt(II)) have been determined by pulse radiolysis to be equal to 5.4 x 10(9) and 6.4 x 10(9) M-1 s(-1), respectively. The efficiencies of e(t)(-) scavenging by EITPt(II) and the rate of e(t)(-) photobleaching have also been determined in LiCl:H2O:CH3OH and MgCl2: H2O : CH3OH glasses, respectively. (C) 1997 Elsevier Science Ltd.

引用

页码：381 / 384

页数：4

共 50 条

[21] FORMATION AND STABILITY OF SILVER(+1) LYATE COMPLEXES IN WATER-METHANOL SOLUTION
PIUZE, J
GUBELI, AO
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (21): : 3250 - 3256
[22] POLAROGRAPHIC STUDY OF SOLVATE COMPLEXES OF ZINC AND CADMIUM IN WATER-METHANOL SOLUTIONS
PAVLOV, NN
GINIATULLIN, NG
LEBEDEV, VM
SAMMAR, M
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1982, 25 (08): : 1018 - 1019
[23] Radiation reduction of binuclear Rh(II) complexes in aqueous-methanol solutions
Kalecinska, E
Kalecinski, J
Pruchnik, FP
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 1998, 232 (1-2) : 97 - 101
[24] Radiation reduction of binuclear Rh(II) complexes in aqueous-methanol solutions
E. Kalecińska
J. Kaleciński
F. P. Pruchnik
Journal of Radioanalytical and Nuclear Chemistry, 1998, 232 : 97 - 101
[25] Room temperature photo-induced deposition of platinum mirrors and nano-layers from simple Pt(II) precursor complexes in water-methanol solutions
Xian, Liang
Engelbrecht, Leon
Barkhuysen, Shani
Koch, Klaus R.
RSC ADVANCES, 2016, 6 (40) : 34014 - 34018
[26] THE SYSTEM FORMALDEHYDE WATER-METHANOL - THERMODYNAMICS OF SOLVATED AND ASSOCIATED SOLUTIONS
BRANDANI, S
BRANDANI, V
DIGIACOMO, G
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1992, 31 (07) : 1792 - 1798
[27] PRECURSORS OF MOLECULAR-HYDROGEN IN RADIOLYSIS OF THE WATER-METHANOL SYSTEM
FELDMAN, VI
KOVALEV, GV
BELEVSKII, VN
BUGAENKO, LT
DOKLADY AKADEMII NAUK SSSR, 1983, 273 (03): : 659 - 663
[28] MONTE-CARLO MOLECULAR SIMULATION FOR WATER-METHANOL SYSTEM
WU, XW
TENG, T
LI, YG
LU, JF
ACTA CHIMICA SINICA, 1992, 50 (06) : 543 - 548
[29] Thermodynamics of copper(II)-ethylenediamine complex formation in water-methanol mixtures
Repkin, GI
Frolova, LN
Nizkoshapkaya, OA
Shormanov, VA
ZHURNAL NEORGANICHESKOI KHIMII, 1997, 42 (08): : 1370 - 1372
[30] A STUDY OF COMPLEX EQUILIBRIA OF PHENYLGLYCINE WITH NICKEL(II), COPPER(II) AND ZINC(II) IN WATER AND IN WATER-METHANOL SOLUTION
LOMOZIK, L
MONATSHEFTE FUR CHEMIE, 1984, 115 (8-9): : 921 - 926

← 1 2 3 4 5 →