Semi In Situ Synthesis of NHTS: A New Hollow Titanium Silicalite Modified by a Noble Metal

被引：7

作者：

Shi, Chunfeng ^{[1
]}

Zhu, Bin ^{[1
]}

Lin, Min ^{[1
]}

Long, Jun ^{[1
]}

机构：

[1] SINOPEC, RIPP, State Key Lab Catalyt Mat & React Engn, Beijing 100083, Peoples R China

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 21期

关键词：

Zeolites; Hydrothermal synthesis; Titanium silicalite; Noble metals; Palladium; Mesoporous materials; CATALYTIC-PROPERTIES; SIPW-X; FT-IR; EPOXIDATION; TS-1; PROPYLENE; STABILITY; COMPOSITE; CRYSTALS; O-2;

D O I：

10.1002/ejic.200900321

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new hollow titanium silicalite with a noble metal incorporated into it (denoted as NHTS) was synthesized by a semi in situ method. This NHTS has intraparticle voids and exhibits bifunctional catalytic performance. It was characterized by various techniques, and its catalytic performance for the direct epoxidation of propylene was investigated. The results show that NHTS, with a highly ordered MFI topological and hollow structure, together with a noble metal, can be employed in catalytic oxidations. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：3067 / 3070

页数：4

共 19 条

[1]

Boccuti M.R., 1989, STUD SURF SCI CATAL, V48, P133

[2] Direct synthesis of H2O2 from O2 and H2 over precious metal loaded TS-1 in CO2 [J].

Chen, Qunlai ;

Beckman, Eric J. .

GREEN CHEMISTRY, 2007, 9 (07) :802-808

[3] Enhancement of Au capture efficiency and activity of Au/TS-1 catalysts for propylene epoxidation [J].

Cumaranatunge, L ;

Delgass, WN .

JOURNAL OF CATALYSIS, 2005, 232 (01) :38-42

[4] Characterization of catalysts based on titanium silicalite, TS-1, by physicochemical techniques [J].

Duprey, E ;

Beaunier, P ;

SpringuelHuet, MA ;

BozonVerduraz, E ;

Fraissard, J ;

Manoli, JM ;

Bregeault, JM .

JOURNAL OF CATALYSIS, 1997, 165 (01) :22-32

[5] Heat-treatment of isomorphously substituted ZSM-5 zeolites and its structural consequences -: An X-ray diffraction, 29Si MAS-NMR, XPS and FT-IR spectroscopy study [J].

Fejes, P ;

Nagy, JB ;

Halász, J ;

Oszkó, A .

APPLIED CATALYSIS A-GENERAL, 1998, 175 (1-2) :89-104

[6]

LIN M, 2002, Patent No. 1089279

[7] Stability and selectivity of Au/TiO2 and Au/TiO2/SiO2 catalysts in propene epoxidation:: An in situ FT-IR study [J].

Mul, G ;

Zwijnenburg, A ;

van der Linden, B ;

Makkee, M ;

Moulijn, JA .

JOURNAL OF CATALYSIS, 2001, 201 (01) :128-137

[8] The role of gold in gold-titania epoxidation catalysts [J].

Nijhuis, TAR ;

Visser, T ;

Weckhuysen, BM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (07) :1115-1118

[9] Vibrational structure of titanium silicate catalysts.: A spectroscopic and theoretical study [J].

Ricchiardi, G ;

Damin, A ;

Bordiga, S ;

Lamberti, C ;

Spanò, G ;

Rivetti, F ;

Zecchina, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (46) :11409-11419

[10] Methanol synthesis from carbon monoxide and hydrogen catalyzed over Pd/CeO2 prepared by the deposition-precipitation method [J].

Shen, WJ ;

Ichihashi, Y ;

Okumura, M ;

Matsumura, Y .

CATALYSIS LETTERS, 2000, 64 (01) :23-25

← 1 2 →