A practical synthesis of 1,4-diiodo-2,5-bis(chloromethyl)benzene and 1,4-diiodo-2,5-bis(bromomethyl)benzene

被引：15

作者：

Gaefke, Gerald

Enkelmann, Volker

Hoeger, Sigurd

机构：

[1] Univ Karlsruhe, TH, Inst Tech Chem & Polymerchem, D-76131 Karlsruhe, Germany

[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

SYNTHESIS-STUTTGART | 2006年 / 17卷 / 17期

关键词：

halogenation; Appel reaction; substituted aromatic alkyl halides; arenes;

D O I：

10.1055/s-2006-942534

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iodination of protected bis(hydroxymethyl)benzene, deprotection of the resulting diiodo aromatics, and subsequent transformation of the hydroxymethyl groups to benzyl halides provides an easy and reliable way to the pure title compounds.

引用

页码：2971 / 2973

页数：3

共 15 条

[1] Functionalized homoleptic cis- and trans-C,N-ortho-chelated aminoaryl platinum(II) complexes [J].

Amijs, CHM ;

van Klink, GPM ;

Lutz, M ;

Spek, AL ;

van Koten, G .

ORGANOMETALLICS, 2005, 24 (12) :2944-2958

[2] TERTIARY PHOSPHANE-TETRACHLOROMETHANE, A VERSATILE REAGENT FOR CHLORINATION, DEHYDRATION, AND P-N LINKAGE [J].

APPEL, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (12) :801-811

[3] DESIGN AND SYNTHESIS OF A MOLECULAR TURNSTILE [J].

BEDARD, TC ;

MOORE, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (43) :10662-10671

[4] Polycyclic aromatic hydrocarbons by ring-closing metathesis [J].

Bonifacio, MC ;

Robertson, CR ;

Jung, JY ;

King, BT .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (21) :8522-8526

[5] Synthesis and characterization of comb-like polyphenylenes via Suzuki coupling of polystyrene macromonomers prepared by atom transfer radical polymerization [J].

Cianga, I ;

Yagci, Y .

EUROPEAN POLYMER JOURNAL, 2002, 38 (04) :695-703

[6] A POLY(P-PHENYLENE) DECORATED WITH FRECHET-TYPE DENDRITIC FRAGMENTS OF THE FIRST-GENERATION [J].

CLAUSSEN, W ;

SCHULTE, N ;

SCHLUTER, AD .

MACROMOLECULAR RAPID COMMUNICATIONS, 1995, 16 (01) :89-94

[7] ADDITION OF ARYL HALIDES TO TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) [J].

FITTON, P ;

RICK, EA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 28 (02) :287-&

[8]

Kay KY, 1997, SYNTHESIS-STUTTGART, P35

[9] SYNTHESIS AND CHARACTERIZATION OF RING-HALOGENATED POLY(1,4-PHENYLENEVINYLENES) [J].

MCCOY, RK ;

KARASZ, FE ;

SARKER, A ;

LAHTI, PM .

CHEMISTRY OF MATERIALS, 1991, 3 (05) :941-947

[10] ADVANCES IN THE SYNTHESIS OF IODOAROMATIC COMPOUNDS [J].

MERKUSHEV, EB .

SYNTHESIS-STUTTGART, 1988, (12) :923-937

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