Fabrication and characterization of a highly sensitive hydroquinone chemical sensor based on iron-doped ZnO nanorods

被引:41
|
作者
Umar, Ahmad [1 ,2 ]
Al-Hajry, Ali [1 ,3 ]
Ahmad, Rafiq [4 ]
Ansari, S. G. [5 ]
Al-Assiri, Mohammed Sultan [1 ,3 ]
Algarni, Hamed [6 ]
机构
[1] Najran Univ, Promising Ctr Sensors & Elect Devices, Najran 11001, Saudi Arabia
[2] Najran Univ, Fac Sci & Arts, Dept Chem, Najran 11001, Saudi Arabia
[3] Najran Univ, Fac Sci & Arts, Dept Phys, Najran 11001, Saudi Arabia
[4] Chonbuk Natl Univ, Sch Semicond & Chem Engn, Nanomat Proc Res, Jeonju 561756, South Korea
[5] Jamia Millia Islamia, Ctr Interdisciplinary Res Basic Sci, New Delhi 110025, India
[6] King Khalid Univ, Dept Phys, Fac Sci, Abha, Saudi Arabia
关键词
GLASSY-CARBON ELECTRODE; ELECTROCHEMICAL-BEHAVIOR; PHOTOCATALYTIC DEGRADATION; MAGNETIC-PROPERTIES; CATECHOL; GRAPHENE; DYE; NANOSTRUCTURES; NANOPARTICLES; TEMPERATURE;
D O I
10.1039/c5dt03364k
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Herein, we report the development of a simple and highly sensitive hydroquinone (HQ) chemical sensor based on an electrochemically activated iron-doped (Fe-doped) zinc oxide nanorod (ZnO NR) modified screen-printed electrode (SPE). The Fe-doped ZnO NRs were prepared using a hydrothermal process and their morphological, crystal, compositional and optical properties were characterized in detail. The detailed characterizations showed that the NRs are densely grown, well-crystalline and possess a wurtzite hexagonal phase. The fabricated HQ electrochemical sensor exhibited high sensitivity of 18.60 mu A mM(-1) cm(-2) and a very low experimental detection limit of 0.51 mu M. Our results demonstrate that simply prepared doped ZnO nanomaterials are promising candidates to fabricate highly sensitive electrochemical sensors.
引用
收藏
页码:21081 / 21087
页数:7
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