Transition Metal Substituted Polyoxotungstates in the Catalytic Oxidation of 1H-Indene and 1,2-Dihydronaphthalene with Hydrogen Peroxide

被引：21

作者：

Estrada, Ana C. ^{[1
]}

Simoes, Mario M. Q. ^{[2
]}

Santos, Isabel C. M. S. ^{[2
]}

Neves, M. Graca P. M. S. ^{[2
]}

Silva, Artur M. S. ^{[2
]}

Cavaleiro, Jose A. S. ^{[2
]}

Cavaleiro, Ana M. V. ^{[1
]}

机构：

[1] Univ Aveiro, Dept Chem, CICECO, P-3810193 Aveiro, Portugal

[2] Univ Aveiro, Dept Chem, QOPNA, P-3810193 Aveiro, Portugal

来源：

CATALYSIS LETTERS | 2009年 / 128卷 / 3-4期

关键词：

1H-indene; 1,2-dihydronaphthalene; Polyoxometalates; Polyoxotungstates; Hydrogen peroxide; Oxidation; STEP ALKENE CLEAVAGE; HETEROPOLY ACIDS; EPOXIDATION; TUNGSTOPHOSPHATES; CYCLOALKANES; EQUIVALENT; COMPLEXES; OXIDE;

D O I：

10.1007/s10562-008-9718-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of 1H-indene and 1,2-dihydronaphthalene with hydrogen peroxide in the presence of Mn(III) or Fe(III) substituted Keggin-type polyoxotungstates is described. The products obtained depend on the catalyst and reaction conditions. Ring cleavage was observed, affording dialdehydes under mild and environmentally friendly conditions. Other main products were the alpha-hydroxy-ketones. The resulting epoxides seem to be intermediates to other oxygenated products.

引用

页码：281 / 289

页数：9

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