Iron-based metal-organic framework, Fe(BTC): an effective dual-functional catalyst for oxidative cyclization of bisnaphthols and tandem synthesis of quinazolin-4(3H)-ones

被引：67
作者：
Oveisi, Ali Reza [1 ]
Khorramabadi-zad, Ahmad [1 ]
Daliran, Saba [1 ]
机构：
[1] Bu Ali Sina Univ, Fac Chem, POB 6517838683, Hamadan, Iran
来源：
RSC ADVANCES | 2016年 / 6卷 / 02期
关键词：
HETEROGENEOUS CATALYSTS; AEROBIC OXIDATION; LEWIS-ACID; EFFICIENT; QUINAZOLINONES; SPIRONAPHTHALENONES; MIL-100(FE);
D O I：
10.1039/c5ra19013d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An iron-based metal-organic framework [Fe(BTC) (BTC: 1,3,5-benzenetricarboxylate)] has been shown to be an active and heterogeneous catalyst for both oxidative cyclization of methylenebisnaphthols and a modern tandem process (an in situ oxidation-aminal formation-oxidation sequence). Such a potential catalytic utility of Fe(BTC) makes it quite attractive for sustainable industrial chemistry.
引用
收藏
页码：1136 / 1142
页数：7
相关论文
共 58 条
[1]   Zeolite-like metal-organic frameworks as platforms for applications:: On metalloporphyrin-based catalysts [J].
Alkordi, Mohamed H. ;
Liu, Yunling ;
Larsen, Randy W. ;
Eubank, Jarrod F. ;
Eddaoudi, Mohamed .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) :12639-+
[2]   SPIRANS .12. STEREOCHEMICAL CONTROL IN THE OXIDATIVE CYCLIZATION OF BIS-NAPHTHOLS [J].
BENNETT, DJ ;
DEAN, FM ;
HERBIN, GA ;
MATKIN, DA ;
PRICE, AW ;
ROBINSON, ML .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1980, (09) :1978-1985
[3]  
Beyzavi MH, 2015, J AM CHEM SOC, V137, P13624, DOI [10.1021/jacs.5b03440, 10.1021/jacs.5b08440]
[4]   A Hafnium-Based Metal Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation [J].
Beyzavi, M. Hassan ;
Klet, Rachel C. ;
Tussupbayev, Samat ;
Borycz, Joshua ;
Vermeulen, Nicolaas A. ;
Cramer, Christopher J. ;
Stoddart, J. Fraser ;
Hupp, Joseph T. ;
Farha, Omar K. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (45) :15861-15864
[5]   The spirodienone route for the functionalization of calixarenes [J].
Biali, SE .
SYNLETT, 2003, (01) :1-11
[6]   Aerobic oxidation catalysis with stable radicals [J].
Cao, Qun ;
Dornan, Laura M. ;
Rogan, Luke ;
Hughes, N. Louise ;
Muldoon, Mark J. .
CHEMICAL COMMUNICATIONS, 2014, 50 (35) :4524-4543
[7]   Synthesis and properties of a new member of the calixnaphthalene family:: A C2-Symmetrical endo-calix[4]naphthalene [J].
Chowdhury, S ;
Georghiou, PE .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (19) :6808-6811
[8]   Quinoxaline synthesis via oxidative cyclization reaction using metal-organic framework Cu(BDC) as an efficient heterogeneous catalyst [J].
Dang, Giao H. ;
Vu, Yen T. H. ;
Dong, Quoc A. ;
Le, Dung T. ;
Thanh Truong ;
Phan, Nam T. S. .
APPLIED CATALYSIS A-GENERAL, 2015, 491 :189-195
[9]  
Davis F., 2011, Macrocycles, P126, DOI [10.1002/9780470980200.ch5, DOI 10.1002/9780470980200.CH5]
[10]   Cascade Reactions Catalyzed by Metal Organic Frameworks [J].
Dhakshinamoorthy, Amarajothi ;
Garcia, Hermenegildo .
CHEMSUSCHEM, 2014, 7 (09) :2392-2410
123456