Synthesis and photoluminescence behavior of Bi4Ti3O12 powders obtained by the complex polymerization method

被引：58

作者：

Oliveira, R. C. ^{[1
]}

Cavalcante, L. S. ^{[1
]}

Sczancoski, J. C. ^{[1
]}

Aguiar, E. C. ^{[2
]}

Espinosa, J. W. M. ^{[2
]}

Varela, J. A. ^{[2
]}

Pizani, P. S. ^{[1
]}

Longo, E. ^{[2
]}

机构：

[1] Univ Fed Sao Carlos, Dept Quim & Fis, LIEC, BR-13565905 Sao Carlos, SP, Brazil

[2] Univ Estadual Paulista, Dept Quim, LIEC IQ, BR-14801907 Araraquara, SP, Brazil

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 478卷 / 1-2期

基金：

巴西圣保罗研究基金会;

关键词：

Clusters; Chemical synthesis; Optical properties; Luminescence; BISMUTH TITANATE NANOCRYSTALS; HYDROTHERMAL SYNTHESIS; ELECTRICAL-PROPERTIES; NEUTRON-DIFFRACTION; CRYSTAL-STRUCTURE; PIEZOELECTRIC PROPERTIES; DIELECTRIC-PROPERTIES; RAMAN-SPECTROSCOPY; OPTICAL-PROPERTIES; CERAMICS;

D O I：

10.1016/j.jallcom.2008.11.115

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bismuth titanate, Bi4Ti3O12(BiT) powders were synthesized by the complex polymerization method. The structural evolution as a function of heat treatment temperature of these powders was analyzed by X-ray diffraction (XRD) and micro-Raman (MR) spectroscopy. The optical properties were verified by ultraviolet-visible (UV-vis) absorption spectroscopy and photoluminescence (PL) measurements. XRD patterns and MR spectra revealed that the BiT powders heat treated at 700 degrees C for 2 h under oxygen flow crystallize in an orthorhombic structure without deleterious phases. UV-vis spectra indicated the presence of intermediary energy levels within the band gap of the powders heat treated at low temperatures. The maximum PL emissions of these materials were verified at around 598 nm, when excited by 488 nm wavelengths. Also, it was observed the presence of two broad PL bands, which were attributed to the intermediary energy levels arising from alpha-Bi2O3 and BiT phases. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：661 / 670

页数：10

共 93 条

[21] Unit cell refinement from powder diffraction data: The use of regression diagnostics [J].

Holland, TJB ;

Redfern, SAT .

MINERALOGICAL MAGAZINE, 1997, 61 (01) :65-77

[22]

Hushur A, 2002, J KOREAN PHYS SOC, V41, P763

[23] Aurivillius ceramics:: Bi4Ti3O12-based piezoelectrics [J].

Jardiel, T. ;

Caballero, A. C. ;

Villegas, M. .

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2008, 116 (1352) :511-518

[24] Crystal structure and spontaneous polarization of Bi4-xNdxTi3O12 studied by using neutron powder diffraction data [J].

Jeon, Min Ku ;

Kim, Yong-Il ;

Nahm, Seung-Hoon ;

Sohn, Jung Min ;

Jung, Chang Hwa ;

Woo, Seong Ihl .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2007, 40 (15) :4647-4652

[25] Crystal structure of Bi4-xCexTi3O12(x=0, 0.25, 0.5 and 0.75) studied by Raman spectroscopy and neutron powder diffraction [J].

Jeon, Min Ku ;

Kim, Yong-Il ;

Nahm, Seung-Hoon ;

Woo, Seong Ihl .

JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2006, 39 (23) :5080-5085

[26] Effect of incorporating nonlanthanoidal indium on optical properties of ferroelectric Bi4Ti3O12 thin films [J].

Jia, Caihong ;

Chen, Yonghai ;

Ding, Linghong ;

Zhang, Weifeng .

APPLIED SURFACE SCIENCE, 2007, 253 (24) :9506-9512

[27] STRUCTURAL AND OPTICAL-PROPERTIES OF FERROELECTRIC BI4TI3O12 THIN-FILMS BY SOL-GEL TECHNIQUE [J].

JOSHI, PC ;

MANSINGH, A ;

KAMALASANAN, MN ;

CHANDRA, S .

APPLIED PHYSICS LETTERS, 1991, 59 (19) :2389-2390

[28]

KAN Y, 2000, MATER LETT, V44, P910

[29] Preparation and properties of neodymium-modified bismuth titanate ceramics [J].

Kan, Yan-Mei ;

Zhang, Guo-Jun ;

Wang, Pei-Ling ;

Cheng, Yi-Bing .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2008, 28 (08) :1641-1647

[30] Low-temperature sintering of Bi4Ti3O12 derived from a co-precipitation method [J].

Kan, YM ;

Wang, PL ;

Li, YX ;

Cheng, YB ;

Yan, DS .

MATERIALS LETTERS, 2002, 56 (06) :910-914

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