Synthesis and photoluminescence behavior of Bi4Ti3O12 powders obtained by the complex polymerization method

被引：58

作者：

Oliveira, R. C. ^{[1
]}

Cavalcante, L. S. ^{[1
]}

Sczancoski, J. C. ^{[1
]}

Aguiar, E. C. ^{[2
]}

Espinosa, J. W. M. ^{[2
]}

Varela, J. A. ^{[2
]}

Pizani, P. S. ^{[1
]}

Longo, E. ^{[2
]}

机构：

[1] Univ Fed Sao Carlos, Dept Quim & Fis, LIEC, BR-13565905 Sao Carlos, SP, Brazil

[2] Univ Estadual Paulista, Dept Quim, LIEC IQ, BR-14801907 Araraquara, SP, Brazil

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2009年 / 478卷 / 1-2期

基金：

巴西圣保罗研究基金会;

关键词：

Clusters; Chemical synthesis; Optical properties; Luminescence; BISMUTH TITANATE NANOCRYSTALS; HYDROTHERMAL SYNTHESIS; ELECTRICAL-PROPERTIES; NEUTRON-DIFFRACTION; CRYSTAL-STRUCTURE; PIEZOELECTRIC PROPERTIES; DIELECTRIC-PROPERTIES; RAMAN-SPECTROSCOPY; OPTICAL-PROPERTIES; CERAMICS;

D O I：

10.1016/j.jallcom.2008.11.115

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bismuth titanate, Bi4Ti3O12(BiT) powders were synthesized by the complex polymerization method. The structural evolution as a function of heat treatment temperature of these powders was analyzed by X-ray diffraction (XRD) and micro-Raman (MR) spectroscopy. The optical properties were verified by ultraviolet-visible (UV-vis) absorption spectroscopy and photoluminescence (PL) measurements. XRD patterns and MR spectra revealed that the BiT powders heat treated at 700 degrees C for 2 h under oxygen flow crystallize in an orthorhombic structure without deleterious phases. UV-vis spectra indicated the presence of intermediary energy levels within the band gap of the powders heat treated at low temperatures. The maximum PL emissions of these materials were verified at around 598 nm, when excited by 488 nm wavelengths. Also, it was observed the presence of two broad PL bands, which were attributed to the intermediary energy levels arising from alpha-Bi2O3 and BiT phases. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：661 / 670

页数：10

共 93 条

[1] Synthesis of bismuth titanate by the urea method [J].

Anilkumar, M ;

Dhage, SR ;

Ravi, V .

MATERIALS LETTERS, 2005, 59 (04) :514-516

[2]

AURIVILLIUS B, 1950, ARK KEMI, V1, P463

[3]

AURIVILLIUS B, 1951, ARK KEMI, V2, P519

[4] Spectroscopic studies of Bi2O3-Li2O-ZnO-B2O3 glasses [J].

Bale, Shashidhar ;

Rao, N. Srinivasa ;

Rahman, Syed .

SOLID STATE SCIENCES, 2008, 10 (03) :326-331

[5] Low temperature neutron diffraction studies on Bi4Ti3O12 [J].

Chakraborty, Keka R. ;

Achary, S. N. ;

Patwe, S. J. ;

Krishna, P. S. R. ;

Shinde, A. B. ;

Tyagi, A. K. .

CERAMICS INTERNATIONAL, 2007, 33 (04) :601-604

[6] The effect of Bi2O3 compensation during thermal treatment on the crystalline and electrical characteristics of bismuth titanate thin films [J].

Chia, Wei-Kuo ;

Yang, Cheng-Fu ;

Chen, Ying-Chung .

CERAMICS INTERNATIONAL, 2008, 34 (02) :379-384

[7] Neutron diffraction and X-ray absorption spectroscopic analyses for lithiated Aurivillius-type layered perovskite oxide, Li2Bi4Ti3O12 [J].

Choy, JH ;

Kim, JY ;

Chung, I .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (33) :7908-7912

[8] ELECTRICAL AND OPTICAL PROPERTIES OF FERROELECTRIC BI4TI3O12 SINGLE CRYSTALS [J].

CUMMINS, SE ;

CROSS, LE .

JOURNAL OF APPLIED PHYSICS, 1968, 39 (05) :2268-&

[9] Synthesis of bismuth titanate by citrate method [J].

Dhage, SR ;

Khollam, YB ;

Dhespande, SB ;

Potdar, HS ;

Ravi, V .

MATERIALS RESEARCH BULLETIN, 2004, 39 (13) :1993-1998

[10] Studies on ferroelectric perovskites and Bi-layered compounds using micro-Raman spectroscopy [J].

Dobal, PS ;

Katiyar, RS .

JOURNAL OF RAMAN SPECTROSCOPY, 2002, 33 (06) :405-423

← 1 2 3 4 5 6 7 8 9 10 →