N-(2-Thienylmethylene)-2-(2-{[2-(2-thienylmethyleneamino)phenyl]sulfanyl}ethylsulfanyl)aniline

被引:1
作者
Kakanejadifard, Ali [1 ]
Amani, Vahid [2 ]
机构
[1] Lorestan Univ, Dept Chem, Fac Sci, Khorramabad, Iran
[2] Islamic Azad Univ, Dept Chem, Shahr e Rey Branch, Tehran, Iran
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
COMPLEXES; BEHAVIOR;
D O I
10.1107/S1600536809024404
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, C(24)H(20)N(2)S(4), contains one half-molecule: a crystallographic centre of inversion is located at the mid-point of the two central C atoms. The thiophene ring is oriented at a dihedral angle of 60.64 (3)degrees with respect to the benzene ring. In the crystal structure, pi-pi contacts between thiophene rings [centroid-centroid distance = 3.581 (1)angstrom] may stabilize the structure. A weak C-H center dot center dot center dot pi interaction is also present.
引用
收藏
页码:01712 / U3597
页数:9
相关论文
共 11 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]  
Bruker, 2005, APEX2 SAINT SADABS
[3]   New oxorhenium(V) complexes with 2N2S donor sets and radiochemical behavior of their technetium analogs [J].
Dhara, PK ;
Das, B ;
Lo, JM ;
Chattopadhyay, P .
APPLIED RADIATION AND ISOTOPES, 2005, 62 (05) :729-735
[4]   THE SYNTHESIS AND COMPLEX-FORMATION OF DIBENZO[E,K]-2,3-BIS(HYDROXYIMINO)-1,4-DIAZA-7,10-DITHIA-2,3,8,9-TETRAHYDROCYCLODODECINE [J].
GOK, Y ;
DEMIRBAS, A .
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1989, 19 (07) :681-698
[5]   (2Z,3Z)-quinoxaline-2,3(1H,4H)-dione dioxime [J].
Kakanejadifard, Ali ;
Amani, Vahid .
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :O1512-U2475
[6]  
Kakanejadifard A, 2007, IRAN J CHEM CHEM ENG, V26, P63
[7]   Synthesis and coordination chemistry of new tetradentate N2S2 donor Schiff-base ligand ca2-dapte: Mononuclear and dinuclear copper(I) complexes [Cu(ca2dapte)]ClO4 and [{Cu(PPh3)(X)}2(ca2dapte)] (X = I and Br) [J].
Morshedi, Mahbod ;
Amirnasr, Mehdi ;
Slawin, Alexandra M. Z. ;
Woollins, J. Derek ;
Khalaji, Aliakbar Dehno .
POLYHEDRON, 2009, 28 (01) :167-171
[8]   Complexation behaviour of hexadentate ligands possessing N2O4 and N2O2S2 cores:: differential reactivity towards Co(II), Ni(II) and Zn(II) salts and structures of the products [J].
Rajsekhar, G ;
Rao, CP ;
Saarenketo, P ;
Nättinen, K ;
Rissanen, K .
NEW JOURNAL OF CHEMISTRY, 2004, 28 (01) :75-84
[9]   C-S bond cleavage by cobalt:: synthesis, characterization and crystal structure determination of 1,2-di-(o-salicylaldiminophenylthio)ethane and its Co(III) product with C-S bond cleaved fragments [J].
Rajsekhar, G ;
Rao, CP ;
Saarenketo, PK ;
Kolehmainen, E ;
Rissanen, K .
INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (09) :649-652
[10]   A short history of SHELX [J].
Sheldrick, George M. .
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122