Magnetically Induced Catalytic Reduction of Biomass-Derived Oxygenated Compounds in Water

被引:23
作者
Cerezo-Navarrete, Christian [1 ]
Marin, Irene Mustieles [2 ]
Garcia-Miquel, Hector [3 ]
Corma, Avelino [1 ]
Chaudret, Bruno [2 ]
Martinez-Prieto, Luis M. [1 ,4 ]
机构
[1] Univ Politecn Valencia UPV, Inst Tecnol Quim, Valencia 46022, Spain
[2] Univ Toulouse, CNRS, LPCNO Lab Phys & Chim Nano Objets, INSA,UPS, F-31077 Toulouse, France
[3] Univ Politecn Valencia, ITEAM Res Inst, Valencia 46022, Spain
[4] Univ Seville US, Inst Invest Quim CSIC, Dept Quim Inorgan, Seville 41092, Spain
关键词
magnetic nanoparticles; core-shell nanoparticles; magnetically induced catalysis; hydrogenation reactions; biomass-derived compounds; HYPERTHERMIA RESPONSE; GAMMA-VALEROLACTONE; CO2; HYDROGENATION; IRON CARBIDE; NANOPARTICLES; CONVERSION; GRAPHENE; HYDRODEOXYGENATION; COMPOSITE; CHEMISTRY;
D O I
10.1021/acscatal.2c01696
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The development of energetically efficient processes for the aqueous reduction of biomass-derived compounds into chemicals is key for the optimal transformation of biomass. Herein we report an early example of the reduction of biomass-derived oxygenated compounds in water by magnetically induced catalysis. Non-coated and carbon-coated core-shell FeCo@Ni magnetic nanoparticles were used as the heating agent and the catalyst simultaneously. In this way it was possible to control the product distribution by adjusting the field amplitude applied during the magnetic catalysis, opening a precedent for this type of catalysis. Finally, the encapsulation of the magnetic nanoparticles in carbon (FeCo@Ni@C) strongly improved the stability of the magnetic catalyst in solution, making its reuse possible up to at least eight times in dioxane and four times in water.
引用
收藏
页码:8462 / 8475
页数:14
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