Exciton binding energy and effective mass of CsPbCI3: a magneto-optical study

被引:59
作者
Baranowski, Michal [1 ]
Plochocka, Paulina [1 ,2 ,3 ]
Su, Rui [4 ]
Legrand, Laurent [5 ]
Barisien, Thierry [5 ]
Bernardot, Frederick [5 ]
Xiong, Qihura [4 ]
Testelin, Christophe [5 ]
Chamarro, Maria [5 ]
机构
[1] Wroclaw Univ Sci & Technol, Fac Fundamental Problems Technol, Dept Expt Phys, Wroclaw, Poland
[2] CNRS UGA UPS INSA, UPR 3228, Lab Natl Champs Magnet Intenses, Grenoble, France
[3] CNRS UGA UPS INSA, Lab Natl Champs Magnet Intenses, UPR 3228, Toulouse, France
[4] Nanyang Technol Univ, Sch Phys & Math Sci, Div Phys & Appl Phys, Singapore, Singapore
[5] Sorbonne Univ, CNRS, UMR 7588, Inst NanoSci Paris,INSP, Paris, France
关键词
LEAD HALIDE PEROVSKITES; PHOTOLUMINESCENCE; NANOCRYSTALS; EMISSION; METHYLAMMONIUM; CONSTANT; GAP;
D O I
10.1364/PRJ.401872
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
High magnetic field spectroscopy has been performed on lead chloride-based perovskite, a material that attracts significant interest for photovoltaic and photonic applications within the past decades. Optical properties being mainly driven by the exciton states, we have measured the fundamental parameters, such as the exciton binding energy, effective mass, and dielectric constant. Among the inorganic halide perovskites, CsPbCI3 owns the largest exciton binding energy and effective mass. This blue emitting compound has also been compared with lower band gap energy perovskites and other semiconducting phases, showing comparable band gap dependences for binding energy and Bohr radius. (C) 2020 Chinese Laser Press
引用
收藏
页码:A50 / A55
页数:6
相关论文
共 53 条
[1]   Giant Fine Structure Splitting of the Bright Exciton in a Bulk MAPbBr3 Single Crystal [J].
Baranowski, Michal ;
Galkowski, Krzysztof ;
Surrente, Alessandro ;
Urban, Joanna ;
Klopotowski, Lukasz ;
Mackowsk, Sebastian ;
Maude, Duncan Kennedy ;
Ben Aich, Rim ;
Boujdaria, Kais ;
Chamarro, Maria ;
Testelin, Christophe ;
Nayak, Pabitra K. ;
Dollmann, Markus ;
Snaith, Henry James ;
Nicholas, Robin John ;
Plochocka, Paulina .
NANO LETTERS, 2019, 19 (10) :7054-7061
[2]   Bright triplet excitons in caesium lead halide perovskites [J].
Becker, Michael A. ;
Vaxenburg, Roman ;
Nedelcu, Georgian ;
Sercel, Peter C. ;
Shabaev, Andrew ;
Mehl, Michael J. ;
Michopoulos, John G. ;
Lambrakos, Samuel G. ;
Bernstein, Noam ;
Lyons, John L. ;
Stoferle, Thilo ;
Mahrt, Rainer F. ;
Kovalenko, Maksym V. ;
Norris, David J. ;
Raino, Gabriele ;
Efros, Alexander L. .
NATURE, 2018, 553 (7687) :189-+
[3]   Multiband k•p Model for Tetragonal Crystals: Application to Hybrid Halide Perovskite Nanocrystals [J].
Ben Aich, R. ;
Ben Radhia, S. ;
Boujdaria, K. ;
Chamarro, M. ;
Testelin, C. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2020, 11 (03) :808-817
[4]   Bright-Exciton Splittings in Inorganic Cesium Lead Halide Perovskite Nanocrystals [J].
Ben Aich, R. ;
Saidi, I. ;
Ben Radhia, S. ;
Boujdaria, K. ;
Barisien, T. ;
Legrand, L. ;
Bernardot, F. ;
Chamarro, M. ;
Testelin, C. .
PHYSICAL REVIEW APPLIED, 2019, 11 (03)
[5]   Room-Temperature Cavity Polaritons with 3D Hybrid Perovskite: Toward Large-Surface Polaritonic Devices [J].
Bouteyre, Paul ;
Hai Son Nguyen ;
Lauret, Jean-Sebastien ;
Trippe-Allard, Gaelle ;
Delport, Geraud ;
Ledee, Ferdinand ;
Diab, Hiba ;
Belarouci, Ali ;
Seassal, Christian ;
Garrot, Damien ;
Bretenaker, Fabien ;
Deleporte, Emmanuelle .
ACS PHOTONICS, 2019, 6 (07) :1804-1811
[6]   CORRELATION BETWEEN STATIC DIELECTRIC-CONSTANT AND MINIMUM ENERGY-GAP [J].
CHADI, DJ ;
COHEN, ML .
PHYSICS LETTERS A, 1974, A 49 (05) :381-382
[7]   EMPIRICAL RELATION BETWEEN ENERGY-GAP AND LATTICE-CONSTANT IN CUBIC SEMICONDUCTORS [J].
DALVEN, R .
PHYSICAL REVIEW B, 1973, 8 (12) :6033-6034
[8]   Solution-processed hybrid perovskite photodetectors with high detectivity [J].
Dou, Letian ;
Yang, Yang ;
You, Jingbi ;
Hong, Ziruo ;
Chang, Wei-Hsuan ;
Li, Gang ;
Yang, Yang .
NATURE COMMUNICATIONS, 2014, 5
[9]   CESIUM-TRIHALOGEN-PLUMBATES A NEW CLASS OF IONIC SEMICONDUCTORS [J].
FROHLICH, D ;
HEIDRICH, K ;
KUNZEL, H ;
TRENDEL, G ;
TREUSCH, J .
JOURNAL OF LUMINESCENCE, 1979, 18-9 (JAN) :385-388
[10]   Excitonic Properties of Low-Band-Gap Lead-Tin Halide Perovskites [J].
Galkowski, Krzysztof ;
Surrente, Alessandro ;
Baranowski, Michal ;
Zhao, Baodan ;
Yang, Zhuo ;
Sadhanala, Aditya ;
Mackowski, Sebastian ;
Stranks, Samuel D. ;
Plochocka, Paulina .
ACS ENERGY LETTERS, 2019, 4 (03) :615-621