The role of matrix molecular weight in rubber toughened nylon 6 blends .2. Room temperature Izod impact toughness

被引:98
作者
Oshinski, AJ [1 ]
Keskkula, H [1 ]
Paul, DR [1 ]
机构
[1] UNIV TEXAS, CTR POLYMER RES, DEPT CHEM ENGN, AUSTIN, TX 78712 USA
关键词
toughening; Izod impact; nylon; 6;
D O I
10.1016/0032-3861(96)00374-6
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The Izod impact strength of blends of nylon 6 with maleated and non-maleated styrene-hydrogenated butadiene-styrene triblock copolymers, SEBS, and ethylene/propylene random copolymers, EPR, is influenced by the molecular weight of the nylon 6 phase, the rubber particle size, and rubber type. The upper and lower particle size limits for super-toughening were found to be dependent on the polyamide molecular weight and rubber type. The SEES type elastomers produce blends that have higher toughness over a broader range of rubber particle sizes than the EPR/EPR-g-MA mixtures. The effect of nylon 6 molecular weight on the room temperature Izod impact strength of these blends depends on how the comparison is made; however, generally higher levels of toughness can be obtained from the higher molecular weight nylon 6 materials. Copyright (C) 1996 Elsevier Science Ltd.
引用
收藏
页码:4909 / 4918
页数:10
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