The effect of heat treatment on the anatase-rutile phase transformation and photocatalytic activity of Sn-doped TiO2 nanomaterials

被引：46

作者：

Zhu, Xiaodong ^{[1
,2
]}

Han, Shihu ^{[2
]}

Feng, Wei ^{[1
,3
]}

Kong, Qingquan ^{[1
,3
]}

Dong, Zhihong ^{[1
]}

Wang, Chenxi ^{[1
]}

Lei, Jiahao ^{[1
]}

Yi, Qian ^{[1
]}

机构：

[1] Chengdu Univ, Coll Mech Engn, Chengdu 610106, Sichuan, Peoples R China

[2] Chengdu Univ Technol, Coll Mat & Chem & Chem Engn, Chengdu 610059, Sichuan, Peoples R China

[3] Sichuan Univ, Coll Architecture & Environm, Chengdu 610065, Sichuan, Peoples R China

来源：

RSC ADVANCES | 2018年 / 8卷 / 26期

关键词：

VISIBLE-LIGHT; DEGRADATION; PERFORMANCE; UV; NANOPARTICLES; FE3+;

D O I：

10.1039/c8ra00766g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sn-doped TiO2 nanomaterials with different amounts of Sn (1, 2.5, 5, 10, and 15 at%) were prepared by a sol-gel method and characterized by XRD, TG, DTA, EDS, XPS, DRS, SEM, BET, and PL. The photocatalytic activity of the prepared samples was investigated by measuring the degradation of rhodamine B in aqueous solution under UV light. The experimental results indicate that doping with Sn promotes phase transformation from anatase to rutile. The photocatalytic activity of TiO2 is influenced by both the heat treatment temperature and the Sn doping concentration. 1% Sn-TiO2 exhibits the highest degradation rate at 350 degrees C and 5% Sn-TiO2 exhibits the best photocatalytic activity at 500 degrees C and 650 degrees C. The enhancement of the photocatalytic activity can be ascribed to a larger surface area and a better hydration ability, as well as less recombination of the photogenerated pairs.

引用

页码：14249 / 14257

页数：9

共 44 条

[11] THE INFLUENCE OF ALUMINA DOPANT ON THE STRUCTURAL TRANSFORMATION OF GEL-DERIVED NANOMETER TITANIA POWDERS [J].

DING, XZ ;

LIU, L ;

MA, XM ;

QI, ZZ ;

HE, YZ .

JOURNAL OF MATERIALS SCIENCE LETTERS, 1994, 13 (06) :462-464

[12] Photocatalytic Activity vs Structural Features of Titanium Dioxide Materials Singly Doped or Codoped with Fluorine and Boron [J].

Dozzi, Maria Vittoria ;

Artiglia, Luca ;

Granozzi, Gaetano ;

Ohtani, Bunsho ;

Selli, Elena .

JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (44) :25579-25589

[13] Influence of Sn source on the performance of dye-sensitized solar cells based on Sn-doped TiO2 photoanodes: A strategy for choosing an appropriate doping source [J].

Duan, Yandong ;

Fu, Nianqing ;

Zhang, Qian ;

Fang, Yanyan ;

Zhou, Xiaowen ;

Lin, Yuan .

ELECTROCHIMICA ACTA, 2013, 107 :473-480

[14] Effects of heat and peroxide treatment on photocatalytic activity of titanate nanotubes [J].

Erjavec, Bostjan ;

Kaplan, Renata ;

Pintar, Albin .

CATALYSIS TODAY, 2015, 241 :15-24

[15] Effect of Sn4+ doping on the photoactivity inhibition and near infrared reflectance property of mica-titania pigments for a solar reflective coating [J].

Gao, Qiang ;

Wu, Xiaomei ;

Ma, Yehong ;

Li, Dianquan ;

Fan, Yueming ;

Du, Chang .

CERAMICS INTERNATIONAL, 2016, 42 (15) :17148-17153

[16] Preparation of N,F-codoped TiO2 nanoparticles by three different methods and comparison of visible-light photocatalytic performances [J].

Guo, Qing ;

Zhang, Zhaohong ;

Ma, Xiping ;

Jing, Kui ;

Shen, Manli ;

Yu, Ning ;

Tang, Jianhua ;

Dionysiou, Dionysios D. .

SEPARATION AND PURIFICATION TECHNOLOGY, 2017, 175 :305-313

[17] Carbamazepine degradation using a N-doped TiO2 coated photocatalytic membrane reactor: Influence of physical parameters [J].

Horovitz, Inna ;

Avisar, Dror ;

Baker, Mark A. ;

Grilli, Rossana ;

Lozzi, Luca ;

Di Camillo, Daniela ;

Mamane, Hadas .

JOURNAL OF HAZARDOUS MATERIALS, 2016, 310 :98-107

[18] Synthesis of samarium- and nitrogen-co-doped TiO2 by modified hydrothermal method and its photocatalytic performance for the degradation of 4-chlorophenol [J].

Huang, D. G. ;

Liao, S. J. ;

Zhou, W. B. ;

Quan, S. Q. ;

Liu, L. ;

He, Z. J. ;

Wan, J. B. .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2009, 70 (05) :853-859

[19] Cobalt ion-doped TiO2 photocatalyst response to visible light [J].

Iwasaki, M ;

Hara, M ;

Kawada, H ;

Tada, H ;

Ito, S .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 224 (01) :202-204

[20] The synthesis of nano-sized undoped, Bi doped and Bi, Cu co-doped SrTiO3 using two solegel methods to enhance the photocatalytic performance for the degradation of dibutyl phthalate under visible light [J].

Jamil, Tarek S. ;

Abbas, Hussien A. ;

Youssief, Ahmed M. ;

Mansor, Eman S. ;

Hammad, Fadwa F. .

COMPTES RENDUS CHIMIE, 2017, 20 (02) :97-106

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