The Auto-Combustion Method Synthesized Eu2O3- ZnO Nanostructured Composites for Electronic and Photocatalytic Applications

被引:21
作者
AlAbdulaal, Thekrayat H. [1 ]
Ganesh, Vanga [1 ]
AlShadidi, Manal [1 ]
Hussien, Mai S. A. [2 ,3 ]
Bouzidi, Abdelfatteh [4 ,5 ]
Algarni, Hamed [1 ]
Zahran, Heba Y. [1 ,3 ]
Abdel-wahab, Mohamed Sh. [6 ]
Yahia, Ibrahim S. [1 ,7 ]
Nasr, Samia [8 ,9 ]
机构
[1] King Khalid Univ, Dept Phys, Fac Sci, Lab Nanosmart Mat Sci & Technol LNSMST, POB 9004, Abha 61413, Saudi Arabia
[2] Ain Shams Univ, Fac Educ, Dept Chem, Cairo 11757, Egypt
[3] Ain Shams Univ, Fac Educ, Nanosc Lab Environm & Biomed Applicat NLEBA, Semicond Lab,Met Lab,Dept Phys, Cairo 11757, Egypt
[4] Univ Sfax, Fac Sci, Phys Insulating & Semiinsulating Mat, Res Unit, BP 1171, Sfax 3000, Tunisia
[5] Shaqra Univ, Al Quwayiyah Branch, Preparatory Year Program, Sahqra 19248, Saudi Arabia
[6] Beni Suef Univ, Fac Postgrad Studies Adv Sci, Mat Sci & Nanotechnol Dept, Bani Suwayf 62511, Egypt
[7] King Khalid Univ, Res Ctr Adv Mat Sci RCAMS, POB 9004, Abha 61413, Saudi Arabia
[8] King Khaled Univ, Fac Sci & Arts Touhama, Dept Chem, Muhayil Asir 63311, Saudi Arabia
[9] Preparatory Inst Engn Studies, Electrochem Mat & Environm, Kairouan 3100, Tunisia
关键词
combustion method; Eu2O3-ZnO nanostructured composites; structural; optical; electrical; photocatalytic activity; ND-DOPED ZNO; METHYLENE-BLUE; AZO DYES; DEGRADATION; EU; PERFORMANCE; PHOTOLUMINESCENCE; PHENOL; TIO2; CONDUCTIVITY;
D O I
10.3390/ma15093257
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An efficient and environmentally friendly combustion technique was employed to produce ZnO nanopowders with different Eu concentrations (from 0.001 g to 5 g). The structural morphology of the Eu2O3-ZnO nanocomposites was examined using XRD, SEM, and infrared spectroscopy (FT-IR). In addition, UV-Vis diffuse reflectance spectroscopy was also used to investigate the effects of europium (Eu) dopant on the optical behaviors and energy bandgaps of nano-complex oxides. The photocatalytic degradation efficiency of phenol and methylene blue was investigated using all the prepared Eu2O3-ZnO nanostructured samples. Photocatalytic effectiveness increased when europium (Eu) doping ratios increased. After adding moderate Eu, more hydroxyl radicals were generated over ZnO. The best photocatalyst for phenol degradation was 1 percent Eu2O3-ZnO, while it was 0.5 percent Eu2O3-ZnO for methylene blue solutions. The obtained Eu2O3-doped ZnO nanostructured materials are considered innovative, promising candidates for a wide range of nano-applications, including biomedical and photocatalytic degradation of organic dyes and phenol.
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页数:22
相关论文
共 75 条
[1]   Synthesis, diffused reflectance and electrical properties of nanocrystalline Fe-doped ZnO via sol-gel calcination technique [J].
Aydin, C. ;
Abd El-sadek, M. S. ;
Zheng, Kaibo ;
Yahia, I. S. ;
Yakuphanoglu, F. .
OPTICS AND LASER TECHNOLOGY, 2013, 48 :447-452
[2]   Effects of precursor, temperature, surface area and excitation wavelength on photoluminescence of ZnO/mesoporous silica nanocomposite [J].
Babu, K. Sowri ;
Reddy, A. Ramachandra ;
Sujatha, Ch. ;
Reddy, K. Venugopal .
CERAMICS INTERNATIONAL, 2013, 39 (03) :3055-3064
[3]   Solar active ZnO-Eu2O3 for energy and environmental applications [J].
Balachandran, S. ;
Jothi, K. Jeeva ;
Selvakumar, K. ;
Bhat, D. K. ;
Sathiyanarayanan, K. ;
Swaminathan, M. .
MATERIALS CHEMISTRY AND PHYSICS, 2020, 256
[4]   Characterization of 2,4-dinitrophenol uptake by Rhodobacter capsulatus [J].
Blasco, R ;
Castillo, F .
PESTICIDE BIOCHEMISTRY AND PHYSIOLOGY, 1997, 58 (01) :1-6
[5]   CRITICAL-REVIEW OF RATE CONSTANTS FOR REACTIONS OF HYDRATED ELECTRONS, HYDROGEN-ATOMS AND HYDROXYL RADICALS (.OH/.O-) IN AQUEOUS-SOLUTION [J].
BUXTON, GV ;
GREENSTOCK, CL ;
HELMAN, WP ;
ROSS, AB .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1988, 17 (02) :513-886
[6]  
Callister W.D., 1997, MAT SCI ENG INTRO
[7]   Photocatalytic degradation of PCP-Na over BiOI nanosheets under simulated sunlight irradiation [J].
Chang, Xiaofeng ;
Huang, Jun ;
Tan, Quanyin ;
Wang, Mo ;
Ji, Guangbin ;
Deng, Shubo ;
Yu, Gang .
CATALYSIS COMMUNICATIONS, 2009, 10 (15) :1957-1961
[8]   Annealing effects on the properties of Nd containing ZnO nanoparticles prepared by sol-gel process [J].
Chao, Liang-Chiun ;
Huang, Jian-Wei ;
Chang, Chung-Wen .
PHYSICA B-CONDENSED MATTER, 2009, 404 (8-11) :1301-1304
[9]   Glycols functionalized fluorescent Eu2O3 nanoparticles: Functionalization effect on the structural and optical properties [J].
Chaudhary, Savita ;
Umar, Ahmad .
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 682 :160-169
[10]   Structural, vibrational, optical and magnetic properties of sol-gel derived Nd doped ZnO nanoparticles [J].
Chauhan, Sunil ;
Kumar, Manoj ;
Chhoker, Sandeep ;
Katyal, S. C. ;
Awana, V. P. S. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2013, 24 (12) :5102-5110