Ultrasonic-assisted acid cleaning of nanofiltration membranes fouled by inorganic scales in arsenic-rich brackish water

被引:37
|
作者
Wang, Jian [1 ,2 ]
Gao, Xueli [1 ,2 ]
Xu, Yuan [1 ,2 ]
Wang, Qun [1 ,2 ]
Zhang, Yushan [3 ]
Wang, Xinyan [4 ]
Gao, Congjie [1 ,2 ]
机构
[1] Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Shandong, Peoples R China
[2] Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Shandong, Peoples R China
[3] State Ocean Adm, Inst Tianjin Seawater Desalinat & Multipurpose Ut, Tianjin 300192, Peoples R China
[4] Shandong Zhaojin Mot Co Ltd, Zhaoyuan 265400, Peoples R China
关键词
Nanofiltration membrane; Inorganic scales; Ultrasonic-assisted chemical cleaning; Arsenic-rich brackish water; TIME-DOMAIN REFLECTOMETRY; ULTRAFILTRATION MEMBRANES; MICROFILTRATION MEMBRANES; POLYMERIC MEMBRANES; CERAMIC MEMBRANES; FILTRATION; OPTIMIZATION; IRRADIATION; FREQUENCY;
D O I
10.1016/j.desal.2015.09.021
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This work studied the feasibility of ultrasonic-assisted (US-assisted) chemical cleaning of nanofiltration (NF) membranes that fouled with inorganic scales. We carried out US-assisted acid cleaning experiments by filter arsenic-rich brackish water to investigate the influencing conditions of US-assisted cleaning technology. We first optimized the proper ultrasonic power intensity (1 W/cm(2)) in avoiding of membrane damage. US-assisted water flushing can recover the membrane water flux by around 75%, which suggested that the removal of inorganic scales was inadequate. However, US-assisted add cleaning is efficient for removing the inorganic scales on membrane surface, and cleaning time was significantly shortened by 1/3 to 2/3 when compared with acid cleaning. It is worth to note that US-assisted acid cleaning can be carried out at a lower pH value of 3.0, while traditional acid cleaning usually conducted at pH of 2.0. This would reduce disposal amount of chemical contaminants by up to 90%. Additionally, our investigation suggests the optimal temperature for US-assisted acid cleaning was around 30 degrees C. This study revealed that the US-assisted acid cleaning method is an effective and environmental-friendly method for NF membrane cleaning. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:172 / 177
页数:6
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