Ultrasonic-assisted acid cleaning of nanofiltration membranes fouled by inorganic scales in arsenic-rich brackish water

被引:38
作者
Wang, Jian [1 ,2 ]
Gao, Xueli [1 ,2 ]
Xu, Yuan [1 ,2 ]
Wang, Qun [1 ,2 ]
Zhang, Yushan [3 ]
Wang, Xinyan [4 ]
Gao, Congjie [1 ,2 ]
机构
[1] Ocean Univ China, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Shandong, Peoples R China
[2] Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Shandong, Peoples R China
[3] State Ocean Adm, Inst Tianjin Seawater Desalinat & Multipurpose Ut, Tianjin 300192, Peoples R China
[4] Shandong Zhaojin Mot Co Ltd, Zhaoyuan 265400, Peoples R China
关键词
Nanofiltration membrane; Inorganic scales; Ultrasonic-assisted chemical cleaning; Arsenic-rich brackish water; TIME-DOMAIN REFLECTOMETRY; ULTRAFILTRATION MEMBRANES; MICROFILTRATION MEMBRANES; POLYMERIC MEMBRANES; CERAMIC MEMBRANES; FILTRATION; OPTIMIZATION; IRRADIATION; FREQUENCY;
D O I
10.1016/j.desal.2015.09.021
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This work studied the feasibility of ultrasonic-assisted (US-assisted) chemical cleaning of nanofiltration (NF) membranes that fouled with inorganic scales. We carried out US-assisted acid cleaning experiments by filter arsenic-rich brackish water to investigate the influencing conditions of US-assisted cleaning technology. We first optimized the proper ultrasonic power intensity (1 W/cm(2)) in avoiding of membrane damage. US-assisted water flushing can recover the membrane water flux by around 75%, which suggested that the removal of inorganic scales was inadequate. However, US-assisted add cleaning is efficient for removing the inorganic scales on membrane surface, and cleaning time was significantly shortened by 1/3 to 2/3 when compared with acid cleaning. It is worth to note that US-assisted acid cleaning can be carried out at a lower pH value of 3.0, while traditional acid cleaning usually conducted at pH of 2.0. This would reduce disposal amount of chemical contaminants by up to 90%. Additionally, our investigation suggests the optimal temperature for US-assisted acid cleaning was around 30 degrees C. This study revealed that the US-assisted acid cleaning method is an effective and environmental-friendly method for NF membrane cleaning. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:172 / 177
页数:6
相关论文
共 31 条
[1]   Fouling strategies and the cleaning system of NF membranes and factors affecting cleaning efficiency [J].
Al-Amoudi, Ahmed ;
Lovitt, Robert W. .
JOURNAL OF MEMBRANE SCIENCE, 2007, 303 (1-2) :6-28
[2]   Study and optimization of the ultrasound-enhanced cleaning of an ultrafiltration ceramic membrane through a combined experimental-statistical approach [J].
Alventosa-deLara, E. ;
Barredo-Damas, S. ;
Alcaina-Miranda, M. I. ;
Iborra-Clar, M. I. .
ULTRASONICS SONOCHEMISTRY, 2014, 21 (03) :1222-1234
[3]   Mechanisms for the enhancement of ultrafiltration and membrane cleaning by different ultrasonic frequencies [J].
Cai, Ming ;
Zhao, Shuna ;
Liang, Hanhua .
DESALINATION, 2010, 263 (1-3) :133-138
[4]   Effects of ultrasound on ultrafiltration of Radix astragalus extract and cleaning of fouled membrane [J].
Cai, Ming ;
Wang, Sanju ;
Zheng, Yongping ;
Liang, Hanhua .
SEPARATION AND PURIFICATION TECHNOLOGY, 2009, 68 (03) :351-356
[5]   Effects of concentration polarization, temperature and pressure on ultrasound detection of inorganic fouling and cleaning in a spiral-wound membrane module [J].
Chai, G. Y. ;
Cao, Bing ;
Zhao, G. Y. ;
Greenberg, Alan R. ;
Krantz, W. B. .
DESALINATION AND WATER TREATMENT, 2012, 50 (1-3) :411-422
[6]   Ultrasound-associated cleaning of polymeric membranes for water treatment [J].
Chai, XJ ;
Kobayashi, T ;
Fujii, N .
SEPARATION AND PURIFICATION TECHNOLOGY, 1999, 15 (02) :139-146
[7]   Cleaning of ultrafiltration membranes fouled with BSA by means of saline solutions [J].
Corbaton-Baguena, Maria-Jose ;
Alvarez-Blanco, Silvia ;
Vincent-Vela, Maria-Cinta .
SEPARATION AND PURIFICATION TECHNOLOGY, 2014, 125 :1-10
[8]   Ultrasonic defouling of reverse osmosis membranes used to treat wastewater effluents [J].
Feng, D. ;
van Deventer, J. S. J. ;
Aldrich, C. .
SEPARATION AND PURIFICATION TECHNOLOGY, 2006, 50 (03) :318-323
[9]   Ultrasound-enhanced membrane-cleaning processes applied water treatments: influence of sonic frequency on filtration treatments [J].
Kobayashi, T ;
Kobayashi, T ;
Hosaka, Y ;
Fujii, N .
ULTRASONICS, 2003, 41 (03) :185-190
[10]   Membrane filtration enhanced by ultrasound:: a review [J].
Kyllönen, HM ;
Pirkonen, P ;
Nyström, M .
DESALINATION, 2005, 181 (1-3) :319-335