Effect of Pb(Ni1/2W1/2)O3 on the Phase Transition Behavior of PbZrO3 Ceramic

被引：1

作者：

Sukkha, Usa ^{[1
,2
]}

Vittayakorn, Wanwilai ^{[1
,2
]}

Muanghlua, Rangson ^{[3
]}

Niemcharoen, Surasak ^{[3
]}

Karbkaew, Amornthep ^{[4
]}

Seeharaj, Panpailin ^{[5
]}

Vittayakorn, Naratip ^{[1
,2
,5
]}

机构：

[1] King Mongkuts Inst Technol Ladkrabang, Coll Nanotechnol, Electroceram Res Lab, Bangkok 10520, Thailand

[2] CHE, ThEp Ctr, Bangkok 10400, Thailand

[3] King Mongkuts Inst Technol Ladkrabang, Dept Elect Engn, Fac Engn, Bangkok 10520, Thailand

[4] King Mongkuts Inst Technol Ladkrabang, Dept Instrumentat & Control, Fac Engn, Bangkok 10520, Thailand

[5] King Mongkuts Inst Technol Ladkrabang, Dept Chem, Adv Mat Res Unit, Fac Sci, Bangkok 10520, Thailand

来源：

FERROELECTRICS | 2013年 / 451卷 / 01期

关键词：

Antiferroelectric; wolframite precursor method; lead zirconate; lead nickel tungsten;

D O I：

10.1080/00150193.2013.838902

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Solid solution of (1-x)PbZrO3-xPb(Ni1/2W1/2)O-3;(1-x)PZ-xPNW ceramics, where x = 0.02-0.10, were prepared by solid state reaction. Dense (1-x)PZ - xPNW ceramics were obtained by sintering at 1,100 degrees C for 4h. Effect of PNW on crystal structure, phase transitions and thermal and electrical properties was investigated using X-ray diffraction, dielectric spectroscopy, hysteresis measurement and differential scanning calorimetry. The results indicated that the solubility limit of the (1-x)PZ-xPNW system was found at x = 0.04. It was proved that the intermediate phase is an antiferroelectric in the PZ-PNW system. Stability of the AFE intermediate phase was seen to improve with increasing PNW content.

引用

页码：30 / 40

页数：11

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