Palladium-indium mediated Barbier-type allylation of aldehydes with allenes

被引：75

作者：

Anwar, U ^{[1
]}

Grigg, R ^{[1
]}

Rasparini, M ^{[1
]}

Savic, V ^{[1
]}

Sridharan, V ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Mol Innovat Divers & Automated Synth Ctr, Leeds LS2 9JT, W Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 08期

关键词：

D O I：

10.1039/b001457p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new allylation reaction of carbonyl compounds using allenes is described; homoallylic alcohols were obtained in moderate to good yields from aryl iodides, allenes and carbonyl compounds and an excellent diastereoselection was exhibited when 2-hydroxycyclohexanone was employed.

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页码：645 / 646

页数：2

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