New functional copolymers of 1-vinyl-1,2,4-triazole with allylamine

被引：0

作者：

Prozorova, Galina F. ^{[1
]}

Emel'yanov, Artem, I ^{[1
]}

Korzhova, Svetlana A. ^{[1
]}

机构：

[1] AE Favorsky Irkutsk Inst Chem SB RAS, 1 AE Favorsky St, Irkutsk 664033, Russia

来源：

IZVESTIYA VUZOV-PRIKLADNAYA KHIMIYA I BIOTEKHNOLOGIYA | 2020年 / 10卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

1-vinyl-1,2,4-triazole; allylamine; radical copolymerization;

D O I：

10.21285/2227-2925-2020-10-3-536-540

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New water-soluble functional copolymers based on 1-vinyl-1,2,4-triazole and allylamine were synthesized under the action of free-radical initiation conditions and azobisisobutyric acid dinitrile..opolymers of various compositions with a molecular weight of 1287-30204 Da were obtained by varying reaction conditions. The structure, molecular weight and physicochemical properties of the copolymers were determined using elemental analysis, IR and NMR H-1-spectroscopy, gel permeation chromatography, potentiometric and turbidimetric titration, as well as dynamic light scattering and thermogravimetric analysis. It was established that the obtained copolymers, exhibiting the properties of high-resistance organic semiconductors, are characterized by a specific electrical conductivity of 10(-13)-10(-14) S/cm and high resistance to thermal destruction (up to 260-280 degrees C). These copolymers are promising as stabilizing polymer matrices in the formation of biologically active water-soluble hybrid organic-inorganic nanocomposites.

引用

页码：536 / 540

页数：5

共 11 条

[1] Generation of spatially ordered metal-polymer nanostructures in the irradiated dispersions of poly(acrylic acid)-poly(vinylimidazole)-Cu2+ complexes [J].

Dagas, Deniz E. ;

Danelyan, Gurgen, V ;

Ghaffarlou, Mohammadreza ;

Zezina, Elena A. ;

Abramchuk, Sergei S. ;

Feldman, Vladimir, I ;

Guven, Olgun ;

Zezin, Alexey A. .

COLLOID AND POLYMER SCIENCE, 2020, 298 (02) :193-202

[2] Water-soluble stable polymer nanocomposites with AuNPs based on the functional poly(1-vinyl-1,2,4-triazole-co-N-vinylpyrrolidone) [J].

Pozdnyakov, A. S. ;

Ivanova, A. A. ;

Emel'yanov, A., I ;

Bolgova, Yu, I ;

Trofimova, O. M. ;

Prozorova, G. F. .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 922

[3] Synthesis and Characterization of Silver-Containing Nanocomposites Based on 1-Vinyl-1,2,4-triazole and Acrylonitrile Copolymer [J].

Pozdnyakov, Alexander S. ;

Emel'yanov, Artem I. ;

Kuznetsova, Nadezhda P. ;

Ermakova, Tamara G. ;

Korzhova, Svetlana A. ;

Khutsishvili, Spartak S. ;

Vakul'skaya, Tamara I. ;

Prozorova, Galina F. .

JOURNAL OF NANOMATERIALS, 2019, 2019

[4] Nontoxic hydrophilic polymeric nanocomposites containing silver nanoparticles with strong antimicrobial activity [J].

Pozdnyakov, Alexander S. ;

Emel'yanov, Artem I. ;

Kuznetsova, Nadezhda P. ;

Ermakova, Tamara G. ;

Fadeeva, Tat'yana V. ;

Sosedova, Larisa M. ;

Prozorova, Galina F. .

INTERNATIONAL JOURNAL OF NANOMEDICINE, 2016, 11 :1295-1304

[5] Synthesis and sorption activity of novel cross-linked 1-vinyl-1,2,4-triazole-(trimethoxysilyl)methyl-2-methacrylate copolymers [J].

Prozorova, Galina ;

Kuznetsova, Nadezhda ;

Shaulina, Lyudmila ;

Bolgova, Yuliya ;

Trofimova, Olga ;

Emel'yanov, Artem ;

Pozdnyakov, Alexander .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2020, 916

[6] Green synthesis of water-soluble nontoxic polymeric nanocomposites containing silver nanoparticles [J].

Prozorova, Galina F. ;

Pozdnyakov, Alexsandr S. ;

Kuznetsova, Nadezhda P. ;

Korzhova, Svetlana A. ;

Emel'yanov, Artem I. ;

Ermakova, Tamara G. ;

Fadeeva, Tat'yana V. ;

Sosedova, Larisa M. .

INTERNATIONAL JOURNAL OF NANOMEDICINE, 2014, 9 :1883-1889

[7]

Prozorova GF, 2018, APPL CHEM BIOTECHNOL, V8, P192, DOI [10.21285/2227-2925-2018-8-4-192-196, DOI 10.21285/2227-2925-2018-8-4-192-196]

[8] Impact of amine additives on the mechanical properties of hydrogen bonding n-conjugated polymers [J].

Shinde, Shekhar ;

Gavvalapalli, Nagarjuna .

POLYMER, 2020, 204

[9] NonToxic Silver/Poly-1-Vinyl-1,2,4-Triazole Nanocomposite Materials with Antibacterial Activity [J].

Shurygina, Irina A. ;

Prozorova, Galina F. ;

Trukhan, Irina S. ;

Korzhova, Svetlana A. ;

Fadeeva, Tatiana V. ;

Pozdnyakov, Alexander S. ;

Dremina, Nataliya N. ;

Emel'yanov, Artem I. ;

Kuznetsova, Nadezhda P. ;

Shurygin, Michael G. .

NANOMATERIALS, 2020, 10 (08) :1-17

[10]

Tiantian GT, 2020, POLYMER, V205

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