Regioselective reduction of 4,6-O-benzylidenes using triethylsilane and BF3•Et2O

被引：115
|
作者：
Debenham, SD [1 ]
Toone, EJ [1 ]
机构：
[1] Duke Univ, Dept Chem, Durham, NC 27708 USA
来源：
TETRAHEDRON-ASYMMETRY | 2000年 / 11卷 / 02期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/S0957-4166(99)00584-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The 4,6-di-O-benzylidene acetals of glucose, mannose, glucosamine, and galactose were regioselectively reduced by triethylsilane in the presence of BF3. Et2O to yield the 6-O-benzyl ethers in good to excellent yields. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：385 / 387
页数：3
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