Electrochemistry for the Generation of Renewable Chemicals: One-Pot Electrochemical Deoxygenation of Xylose to -Valerolactone

被引：10

作者：

James, Olusola O. ^{[1
,2
]}

Sauter, Waldemer ^{[1
]}

Schroeder, Uwe ^{[1
]}

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Environm & Sustainable Chem, Hangenring 30, D-38106 Braunschweig, Germany

[2] Kwara State Univ, Chem Unit, PMB 1530, Ilorin, Nigeria

来源：

CHEMSUSCHEM | 2017年 / 10卷 / 09期

关键词：

cathodic reduction; deoxygenation; oxidation; xylose; -valerolactone; KETO-ENOL TRANSFORMATION; LEVULINIC ACID; ELECTROCATALYTIC HYDROGENATION; POLAROGRAPHIC-REDUCTION; REVERSIBLE HYDRATION; CARBONYL-COMPOUNDS; DL-GLYCERALDEHYDE; AQUEOUS-SOLUTION; CONVERSION; STORAGE;

D O I：

10.1002/cssc.201700209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, the electrochemical conversion of xylose to -valerolactone via carbonyl intermediates is demonstrated. The conversion was achieved in aqueous media and at ambient conditions. This study also demonstrates that the feedstock for production of renewable chemicals and biofuels through electrochemistry can be extended to primary carbohydrate molecules. This is the first report on a one-pot electrochemical deoxygenation of xylose to -valerolactone.

引用

页码：2015 / 2022

页数：8

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