Ordering phenomena and demixing in the quasiternary system Ga2Te3/Hg3Te3/In2Te3

被引：3

作者：

vonWensierski, H ^{[1
]}

Bolwin, H ^{[1
]}

Zeppenfeld, A ^{[1
]}

Leute, V ^{[1
]}

机构：

[1] UNIV MUNSTER,INST PHYS CHEM,D-48149 MUNSTER,GERMANY

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1997年 / 255卷 / 1-2期

关键词：

ordered phases; phase diagrams; phase transitions; solid solutions; structural vacancies; thermodynamics;

D O I：

10.1016/S0925-8388(96)02814-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The phase diagram of the quasiternary system Ga2Te3/Hg3Te3/In2Te3 for the temperature range 650 < T/K < 900 was investigated by X-ray diffraction, by DTA measurements and by electron microprobe analysis. It is shown that ordered structures are formed at special concentrations of structural vacancies. Depending on temperature and concentration, continuous order-disorder transitions could be detected. Besides structural miscibility gaps and a three-phase region, there occurs also a miscibility gap within an ordered region.

引用

页码：169 / 177

页数：9

共 14 条

[1] THE GALLIUM-TELLURIUM SYSTEM [J].

BLACHNIK, R ;

IRLE, E .

JOURNAL OF THE LESS-COMMON METALS, 1985, 113 (01) :L1-L3

[2]

DELVES RT, 1963, J PHYS CHEM SOLIDS, V24, P549, DOI 10.1016/0022-3697(63)90150-1

[3]

Emsley, 1989, ELEMENTS

[4] THERMODYNAMICS AND KINETICS OF THE QUASIBINARY SYSTEM HG(3-3K)IN2KTE3 .1. INVESTIGATIONS BY X-RAY-DIFFRACTION AND DIFFERENTIAL THERMOANALYSIS [J].

LEUTE, V ;

SCHMIDTKE, HM .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1988, 49 (04) :409-420

[5] THE 4 QUASI-BINARY PHASE-DIAGRAMS OF THE QUASITERNARY SYSTEM (HG,PB) (SE,TE) [J].

LEUTE, V ;

KOLLER, HJ .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE, 1986, 149 :213-227

[6] INTERDIFFUSION IN SYSTEMS WITH STRUCTURAL VACANCIES [J].

LEUTE, V ;

ZEPPENFELD, A .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1989, 93 (11) :1227-1230

[7]

LEVITSKAYA TD, 1970, IAN SSSR NEORG MATER, V6, P559

[8] PHASE DIAGRAM OF THE PSEUDO-BINARY SYSTEM In(2)Te(3)-Hg(3)Te(3) [J].

Ray, B. ;

Spencer, P. M. .

SOLID STATE COMMUNICATIONS, 1965, 3 (12) :389-391

[9]

WEAST RC, 1991, HDB CHEM PHYSICS

[10] The phase diagrams of the quasibinary systems HgTe/In2Te3 and CdTe/In2Te3 [J].

Weitze, D ;

Leute, V .

JOURNAL OF ALLOYS AND COMPOUNDS, 1996, 236 (1-2) :229-235

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