An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins

被引：47

作者：

Rebelo, SLH ^{[1
]}

Simoes, MMQ ^{[1
]}

Neves, MGPMS ^{[1
]}

Silva, AMS ^{[1
]}

Cavaleiro, JAS ^{[1
]}

机构：

[1] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 05期

关键词：

D O I：

10.1039/b313683c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient epoxidation, in very high conversions and selectivities, of aromatic hydrocarbons with hydrogen peroxide, in the presence of Mn-III porphyrins [Mn(TDCPP)Cl, Mn(betaNO(2)TDCPP)Cl, Mn(TPFPP)Cl] as catalysts is described; naphthalene and anthracene afford the anti-1,2:3,4-arene dioxides whereas with phenanthrene the 9,10-oxide is obtained.

引用

页码：608 / 609

页数：2

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