An efficient approach for aromatic epoxidation using hydrogen peroxide and Mn(III) porphyrins

被引：47
|
作者：
Rebelo, SLH [1 ]
Simoes, MMQ [1 ]
Neves, MGPMS [1 ]
Silva, AMS [1 ]
Cavaleiro, JAS [1 ]
机构：
[1] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 05期
关键词：
D O I：
10.1039/b313683c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Efficient epoxidation, in very high conversions and selectivities, of aromatic hydrocarbons with hydrogen peroxide, in the presence of Mn-III porphyrins [Mn(TDCPP)Cl, Mn(betaNO(2)TDCPP)Cl, Mn(TPFPP)Cl] as catalysts is described; naphthalene and anthracene afford the anti-1,2:3,4-arene dioxides whereas with phenanthrene the 9,10-oxide is obtained.
引用
收藏
页码：608 / 609
页数：2
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