One-pot solid phase pyrolysis synthesis of nitrogen-doped carbon dots for Fe3+ sensing and bioimaging

被引:101
作者
Rong, Mingcong [1 ,2 ,3 ]
Feng, Yufeng [5 ]
Wang, Yiru [1 ,2 ]
Chen, Xi [1 ,2 ,4 ]
机构
[1] Xiamen Univ, Coll Chem & Chem Engn, Dept Chem, Xiamen 361005, Peoples R China
[2] Xiamen Univ, Coll Chem & Chem Engn, MOE Key Lab Spectrochem Anal & Instrumentat, Xiamen 361005, Peoples R China
[3] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China
[4] Xiamen Univ, State Key Lab Marine Environm Sci, Xiamen 361005, Peoples R China
[5] Xiamen Univ, Affiliated Hosp 1, Xiamen 361005, Peoples R China
基金
中国国家自然科学基金;
关键词
N-C dots; Solid phase pyrolysis; Fe3+; Fluorescence sensing; Cell imaging; GRAPHENE QUANTUM DOTS; ONE-STEP SYNTHESIS; HIGHLY LUMINESCENT; DEEP-ULTRAVIOLET; AQUEOUS-SOLUTION; NANODOTS; IONS; PHOTOLUMINESCENCE; 2,4,6-TRINITROPHENOL; EMISSION;
D O I
10.1016/j.snb.2017.02.014
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Highly fluorescent nitrogen-doped carbon dots (N-C dots) were prepared by an one-pot solid phase pyrolysis method using guanidinium chloride and citric acid as the catalyst, nitrogen and carbon source without any solvents. The synthesized N-C dots emitted intense blue fluorescence with high photostability and stability in high ionic strength. Under optimal conditions, determination for Fe3+ could be completed in 10 min with a wide linearity from 0 to 200 p.M and a detection limit of 100 nM. The proposed method showed potential applications for Fe3+ detection in real samples. Moreover, the N-C dots were explored for cell imaging with excellent biocompatibility and stability, suggesting their great potential in bioimaging. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:868 / 874
页数:7
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