Synthesis, Characterization and Application of 2, 2′- methylene- bis (4,6-di-tert-butyl-phenyl) Phosphate Sodium

被引:6
作者
Huang, Weijiang [1 ]
He, Wentao [1 ]
Yu, Jie [1 ]
Zhang, Kai [1 ]
Qin, Shuhao [1 ]
Gao, Jing [2 ]
机构
[1] Guizhou Univ, Coll Mat & Met, Guiyang 550025, Peoples R China
[2] Guizhou Kumkuat Mat Ltd Co, Guiyang 550014, Peoples R China
来源
RESEARCH IN MATERIALS AND MANUFACTURING TECHNOLOGIES, PTS 1-3 | 2014年 / 835-836卷
基金
中国国家自然科学基金;
关键词
organic phosphate; nucleating agent; polypropylene; synthesis; application; POLYPROPYLENE;
D O I
10.4028/www.scientific.net/AMR.834-836.119
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
2, 2'- methylene- bis (4,6-di-tert-butyl-phenyl) phosphate sodium(NA-11), a nucleator of polypropylene (PP) was high-efficiently prepared with homemade 2,2'-methylene-bis (4,6-di-tert-butyl-phenyl) phosphorus oxychloride as raw materials by means of hydrolysis and neutralization, and the overall yield of the product was 95.9 %. The synthesized product was characterized by Fourier Transform Infrared spectroscopy (FTIR), thermogravimetry (TG), elemental analysis and P-31-NMR. Polypropylene was modified with the synthesized product as a nucleating agent. The results showed that the tensile strength, flexural strength, and the flexural modulus of composites increased by 12.1%, 30.2%, 41.0% respectively when the synthesized product is 0.1wt%, and the haze decreased form 42.9% to 17.3%.
引用
收藏
页码:119 / +
页数:2
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