On Catalysis by Ionic Liquids

被引：239

作者：

Chakraborti, Asit K. ^{[1
]}

Roy, Sudipta Raha ^{[1
]}

机构：

[1] Natl Inst Pharmaceut Educ & Res NIPER, Dept Med Chem, Sas Nagar 160062, Punjab, India

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 20期

关键词：

DESIGN;

D O I：

10.1021/ja900076a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A molecular level mechanism of catalysis by an ionic liquid (IL) is proposed as an "electrophile nucleophile dual activation" through a "relay of cooperative hydrogen bonds and charge-charge interactions". Spectroscopic (H-1 NMR and IR) studies were used to probe the involvement of the C-2 hydrogen and the AcO- anion of [bmim][OAc] in the catalysis for O-t-Boc formation. Ion fishing by MALDI-TOF-TOF MS and MS-MS established the hydrogen bonded clusters

引用

页码：6902 / +

页数：3

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