Catalysts Loading Effect of Tungsten Oxide Catalytic Furfuryl Alcohol Oligomerization

被引：2

作者：

Chan, Xiaojun ^{[1
]}

Roy, Anushka ^{[3
]}

Ooi, Carmenn ^{[2
]}

Yang, Patrick ^{[2
]}

Morais, Fernanda ^{[2
]}

Kim, Taejin ^{[1
,2
]}

机构：

[1] SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11794 USA

[2] Chem & Mol Engn Dept, Stony Brook, NY 11794 USA

[3] Comsewogue High Sch, Port Jefferson Stn, NY 11776 USA

来源：

MATERIALS TODAY-PROCEEDINGS | 2016年 / 3卷 / 02期

关键词：

Furfuryl alcohol oligomerization; Tungsten oxide; Loading effect; ACID CATALYSTS; POLYMERIZATION; CONVERSION; POLYMERS; CARBON;

D O I：

10.1016/j.matpr.2016.01.106

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The WO3 catalysts loading effect on furfuryl alcohol oligomerization was investigated at 100 degrees C and ambient pressure. According to the information provided by GC and GC/MS, the conversion of furfuryl alcohol and selectivity to short chain-length oligomer (C9 similar to C15) and heavy oligomer (>C-19) were calculated with varied catalysts loading. It was found that with increasing the WO3 catalysts loading from 0.1g to 1.2g, the conversion of FA gradually increased up to 27.1% while the selectivity to short chain-length oligomer decreased then leveled off after 0.6g catalysts loading. Oligomer molecular information including C=C and C=O were also confirmed by Infrared Spectroscopy. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：667 / 671

页数：5

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